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Sequential Determination of 13 Elements in Complex Matrices by Stripping Voltammetry with Mixed Complexing Electrolytes

机译:溶出伏安法测定混合基质中的13种元素

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This paper presents the determination of 13 elements in a simultaneous and sequential analysis using solochrome violet (SVRS), chloranilic acid (CA), diethylenetriaminepentaacetic acid (DTPA), dimethylglyoxime (DMG), and oxine as complexing electrolytes. The Methods were applied to determine Al3+, Fe3+, Mo6+, Zn2+, Cd2+, Pb2+, Cu2+, Ni2+, Co2+, Tl+, U6+, V5+, and Cr6+ in fertilizers, plant materials, and foodstuffs. The Method was found to be selective and accurate (82.13-119.03%) for elemental analysis in complex matrices that were previously submitted to a total oxidative digestion step (calcination and wet digestion). Mutual interferences of the elements were systematically investigated. The Sequential Method could be useful for the routine quality control of foodstuffs and fertilizer formulations regarding mineral nutrients or contaminants.
机译:本文介绍了使用独色紫罗兰(SVRS),氯胺酸(CA),二亚乙基三胺五乙酸(DTPA),二甲基乙二肟(DMG)和肟作为络合电解质的同时和顺序分析中13种元素的测定。该方法适用于测定肥料,植物材料和食品中的Al3 +,Fe3 +,Mo6 +,Zn2 +,Cd2 +,Pb2 +,Cu2 +,Ni2 +,Co2 +,Tl +,U6 +,V5 +和Cr6 +。发现该方法对于复杂基质中的元素分析具有选择性和准确性(82.13-119.03%),该元素先前已进行了总的氧化消化步骤(煅烧和湿消化)。系统地研究了元素之间的相互干扰。顺序法可用于食品和肥料配方中有关矿物质营养或污染物的常规质量控制。

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