Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides

Bochenska M; Guzinski M; Kulesza J

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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides

机译：下缘取代了对叔丁基-Calix [4]芳烃。第15部分。基于对叔丁基杯杯[4]芳烃硫代酰胺的Pb（II）离子选择电极

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Tetrasubstituted p-tert-butylcalix[4]arene-thioamides (1-5) were applied as ionophores in ion-selective membrane electrodes (ISE) and were tested towards Pb-selectivity. The selectivity coefficients of the electrodes were determined. The tertiary calix[4]thioamides (1, 2) show remarkable selectivity for Pb(II) cations when compared with respectable calix[4]amides. The electrode membranes with those ligands are stable, the Pb-characteristics are close to nernstian within a wide linear range (-log c = 6-1). Compounds 3-5, the secondary calix[4]thioamides form less stable electrode membranes. Complex formation constants of the ligands 1, 2, 3 and 5 with Pb(II) and some most interfering ions were determined.

机译：将四取代的对叔丁基杯[4]亚芳基硫代酰胺（1-5）作为离子载体应用于离子选择性膜电极（ISE）中，并进行了对Pb选择性的测试。确定电极的选择性系数。与可比的杯[4]酰胺相比，叔杯[4]硫代酰胺（1、2）对Pb（II）阳离子显示出显着的选择性。具有这些配体的电极膜是稳定的，Pb特性在宽线性范围内（-log c = 6-1）接近神经。化合物3-5，第二杯[4]硫代酰胺形成较不稳定的电极膜。确定了配体1、2、3和5与Pb（II）和一些干扰最大的离子的配合物形成常数。

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《Electroanalysis》 |2009年第18期|共7页
作者
Bochenska M; Guzinski M; Kulesza J;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
p-tert-Butylcalix4arene; Thioamides; Ion-selective membrane; electrodes (ISE); Selectivity coefficients; Pb(II)-selectivity; Complex; formation constants; Lead; Membranes;

机译：对叔丁基杯[4]芳烃;硫酰胺;离子选择性膜;电极（ISE）;选择性系数;Pb（II）-选择性;络合物;形成常数;铅;膜;

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1. Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides [J] . Bochenska M, Guzinski M, Kulesza J Electroanalysis . 2009,第17a18期

机译：下缘取代了对叔丁基-Calix [4]芳烃。第15部分。基于对叔丁基杯杯[4]芳烃硫代酰胺的Pb（II）离子选择电极
2. Lower rim substituted p-tert-butyl-calix[4]arene. Part 16. Synthesis of 25,26,27,28-tetrakis(piperidinylthiocarbonylmethylene)-p-tert-butylcalix[4] arene and its interaction with metal ions [J] . Kulesza J., Guzinski M., Hubscher-Bruder V., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2011,第1期

机译：下边缘取代的对叔丁基杯杯[4]芳烃。第16部分。25,26,27,28-四（哌啶基硫代羰基亚甲基）-对叔丁基杯[4]芳烃的合成及其与金属离子的相互作用
3. Lower Rim Substituted tert-Butylcalix[4]arenes. Part 13. Interaction of Calix-hydroxamates with Fe(III) and Pb(II); Studies in Ion-Selective Membrane Electrodes (ISE) [J] . M. Bochenska, U. Lesinska Polish Journal of Chemistry . 2008,第6期

机译：下缘取代了叔丁基杯[4]芳烃。第13部分。杯杯异羟肟酸酯与Fe（III）和Pb（II）的相互作用;离子选择性膜电极（ISE）的研究
4. Cd (II) Ion-Selective Electrode Based On 2-Acetylthiophene Semicarbazone In Polymeric Membrane [C] . C. Mohan, K. Sharma, S. Chandra PRiME Joint International Meeting of the Electrochemical Society, the Electrochemical Society of Japan, and the Korean Electrochemical Society . 2016

机译：CD（II）基于2-乙酰噻吩氨基脲在聚合物膜中的离子选择性电极
5. Lower-rim chemistry of calix(5)arenes, isolation of calix(9--20)arenes, and investigations of the mechanisms of the base-induced and acid-catalyzed calixarene-forming reactions [D] . Stewart, Donald Ralph 1997

机译：杯芳烃（5）芳烃的下边缘化学，杯芳烃（9--20）芳烃的分离，以及碱诱导的和酸催化的杯芳烃形成反应机理的研究
6. Calix4arene Derivative-Modified Glassy Carbon Electrode: A NewSensing Platform for Rapid Simultaneous and Picomolar Detectionof Zn(II) Pb(II) As(III) and Hg(II) [O] . Sundus Sultan, Afzal Shah, *, 2019

机译：杯4芳烃衍生物修饰的玻碳电极：一种新的快速同步和皮摩尔检测的传感平台Zn（II）Pb（II）As（III）和Hg（II）的含量
7. Electronic absorption spectroscopic investigation of the solution binding of Hg(II) and Pd(II) to the upper rim substituted chromogenic calix[4]arene: 5,11-bis-(2-allylthiophenylazo)-25,26,27,28-tetrtahydroxy calix[4]arene and 5,11,17,23-tetrakis-(2-cetylthiophenylazo)-25,26,27,28-tetrahydroxycalix[4]arene [O] . Lukesh Bajaj, H. Mohindra Chawla, Tania Francis, 2005

机译：电子吸收光谱研究Hg（II）和pd（II）与上缘取代生色杯[4]芳烃的溶液结合：5,11-双 - （2-烯丙基噻吩基偶氮）-25,26,27,28-四羟基杯[4]芳烃和5,11,17,23-四 - （2-十六烷基苯并噻唑）-25,26,27,28-四羟基杯[4]芳烃

Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides

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