A glucose sensor based on an aminophenyl boronic acid bonded conducting polymer

Das D.; Kim D.-M.; Park D.-S.; Shim Y.-B.

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A glucose sensor based on an aminophenyl boronic acid bonded conducting polymer

机译：基于氨基苯基硼酸键合导电聚合物的葡萄糖传感器

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3-Aminophenyl boronic acid (APBA) bonded on the conducting polymer layer was prepared and used for detection of saccharides through the complexation between boronic acid and diol groups of saccharide. The probe was prepared by electropolymerization of 5,2':5,2''-terthiophene-3'-carboxylic acid (TTCA), followed by covalent bond formation with APBA. It provides the site for the formation of tetrahedral boronate ester on the polymer layer (pTTCA). Each surface was characterized by CV, XPS, and QCM. Results show a dynamic range between 0.9 and 9.1μM and a detection limit of 0.49μM for glucose. The sensor was also applied for the detection of other saccharides including galactose and mannose. The performance of the sensor was evaluated in a human saliva sample.

机译：制备了键合在导电聚合物层上的3-氨基苯基硼酸（APBA），并通过硼酸与糖的二醇基团之间的络合用于糖的检测。通过5,2'：5,2''-对噻吩-3'-羧酸（TTCA）的电聚合，然后与APBA形成共价键来制备探针。它提供了在聚合物层（pTTCA）上形成四面体硼酸酯的位置。每个表面都有CV，XPS和QCM表征。结果显示动态范围为0.9至9.1μM，葡萄糖的检出限为0.49μM。该传感器还用于检测其他糖类，包括半乳糖和甘露糖。在人类唾液样本中评估了传感器的性能。

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《Electroanalysis》 |2011年第9期|共6页
作者
Das D.; Kim D.-M.; Park D.-S.; Shim Y.-B.;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
Boronic acid derivatives; Conducting polymers; Micromolar level detection; Nonoxidative saccharide sensor; Saliva;

机译：硼酸衍生物导电聚合物微摩尔水平检测非氧化糖传感器唾液;

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1. A glucose sensor based on an aminophenyl boronic acid bonded conducting polymer [J] . Das D., Kim D.-M., Park D.-S., Electroanalysis . 2011,第9期

机译：基于氨基苯基硼酸键合导电聚合物的葡萄糖传感器
2. Development of Amperometric Glucose Biosensor Based on Reconstitution of Glucose Oxidase on Polymeric 3-Aminophenyl Boronic Acid Monolayer [J] . Mehmet ?enel, Cevdet Nergiz, Muamer Dervisevic, Electroanalysis . 2013,第5期

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3. One Pot Synthesis of New Gold Nanoparticles Dispersed Poly(2-aminophenyl boronic acid) Composites for Fabricating an Affinity Based Electrochemical Detection of Glucose [J] . Sai-Anand Gopalan, Gopalan Anantha-Iyengar, Kang Shin-Won, Science of advanced materials . 2014,第7期

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4. Synthesis and Electrochemical Properties of Poly(aniline boronic acid): A Novel Transduction Method for a Non-enzymatic Glucose Sensor and A Precursor Route to Substituted Polyanilines [C] . Eiichi Shoji, Michael S.Freund Meeting of the Electrochemical Society . 2002

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5. Synthesis of boronic acid based sensors for glucose and sialic acid and synthesis of novel and selective PDE4 enzyme inhibitors. [D] . Kaur, Gurpreet. 2006

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6. Responsive Boronic Acid-Decorated (Co)polymers: From Glucose Sensors to Autonomous Drug Delivery [O] . Gertjan Vancoillie, Richard Hoogenboom 2016

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7. Highly selective non-enzymatic electrochemical sensor based on a titanium dioxide nanowire–poly(3-aminophenyl boronic acid)–gold nanoparticle ternary nanocomposite [O] . N. Muthuchamy, A. Gopalan, Kwang-Pill Lee 2018

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8. Enhanced Direct Electron Transport with Glucose Oxidase Immobilized on (Aminophenyl)Boronic Acid Modified Glassy Carbon Electrode [R] . Narasimhan, K., Wingard, L. B. 1986

机译：用（氨基苯基）硼酸修饰玻碳电极固定化葡萄糖氧化酶增强直接电子输运

A glucose sensor based on an aminophenyl boronic acid bonded conducting polymer

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