Electrochemical study of two tris-O-substituted calix[4]arenes: 25,27-dipropoxy-26-hydroxy-28-benzoyloxycalix[4]arene(partial cone) and 25,27-dibenzyl-26-hydroxy-28-benzoyloxy-calix[4]-arene (partial cone). Electro synthesis of the corresponding cali

Louati A; Spraula J; Gabelica V; Kuhn P; Matt D

首页> 外文期刊>Electrochemistry communications >Electrochemical study of two tris-O-substituted calix[4]arenes: 25,27-dipropoxy-26-hydroxy-28-benzoyloxycalix[4]arene(partial cone) and 25,27-dibenzyl-26-hydroxy-28-benzoyloxy-calix[4]-arene (partial cone). Electro synthesis of the corresponding cali

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Electrochemical study of two tris-O-substituted calix[4]arenes: 25,27-dipropoxy-26-hydroxy-28-benzoyloxycalix[4]arene(partial cone) and 25,27-dibenzyl-26-hydroxy-28-benzoyloxy-calix[4]-arene (partial cone). Electro synthesis of the corresponding cali

机译：两种三-O-取代杯[4]芳烃的电化学研究：25,27-二丙氧基-26-羟基-28-苯甲酰氧基杯[4]芳烃（部分圆锥）和25,27-二苄基-26-羟基-28-苯甲酰氧基-calix [4] -arene（部分锥体）。电合成相应的cali

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The anodic oxidation of 25,27-dipropoxy-26-hydroxy-28-benzoyloxycalix[4]arene 1 and 25,27-dibenzyl-26-hydroxy-28-benzoyloxycalix[4]arene 2 in dichloromethane was investigated by electrochemical and spectroclectrochemical techniques. For both, the overall reaction is a two-electron oxidation of the phenolic group according to an ECE mechanism resulting in the ultimate formation of an observable phenoxylium cation. After reaction of the latter with traces of water and subsequent internal electron transfer, the corresponding calix[4]-monoquinones are formed. (c) 2006 Elsevier B.V. All rights reserved.

机译：通过电化学和光谱技术研究了25,27-二丙氧基-26-羟基-28-苯甲酰氧基杯[4]芳烃1和25,27-二苄基-26-羟基-28-苯甲酰氧基杯[4]芳烃2在二氯甲烷中的阳极氧化。。对于两者而言，总反应是根据ECE机理对酚基进行双电子氧化，最终形成可观察到的苯氧基阳离子。在后者与痕量水反应并随后进行内部电子转移后，形成相应的杯[4]-单醌。（c）2006 Elsevier B.V.保留所有权利。

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《Electrochemistry communications》 |2006年第5期|共6页
作者
Louati A; Spraula J; Gabelica V; Kuhn P; Matt D;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
calixarenes; anodic oxidation; electrosynthesis; calix4monoquinone; BINDING PROPERTIES; CALIXlt; 4gt; ARENES; POLAROGRAPHY; OXIDATION;

机译：杯芳烃;阳极氧化;电合成;杯[4]单醌;结合性能;杯芳烃4;芳烃学;氧化;

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1. Electrochemical study of two tris-O-substituted calix[4]arenes: 25,27-dipropoxy-26-hydroxy-28-benzoyloxycalix[4]arene(partial cone) and 25,27-dibenzyl-26-hydroxy-28-benzoyloxy-calix[4]-arene (partial cone). Electro synthesis of the corresponding cali [J] . Louati A, Spraula J, Gabelica V, Electrochemistry communications . 2006,第5期

机译：两种三-O-取代杯[4]芳烃的电化学研究：25,27-二丙氧基-26-羟基-28-苯甲酰氧基杯[4]芳烃（部分圆锥）和25,27-二苄基-26-羟基-28-苯甲酰氧基-calix [4] -arene（部分锥体）。电合成相应的cali
2. Di-ionizable calix[4]arene-1,3-crown-4 ligands in 1,3-alternate, cone, and partial-cone conformations: Synthesis and metal ion extractions [J] . Yang Y., Cao X., Purkiss D.W., Tetrahedron . 2012,第10期

机译：1,3-交替，圆锥和部分圆锥构象的可双离化杯[4]芳烃-1,3-crown-4配体：合成和金属离子萃取
3. Partial cone conformer of 25,27-bis[(methoxycarbonyl)methoxy]-26,28-dipropoxycalix[4]arene [J] . Guo D.-S., Ma J.-P., Zhang G.-Z., Acta Crystallographica Section E: Crystallographic Communications . 2008,第4期

机译：25,27-双[（甲氧基羰基）甲氧基] -26,28-二丙氧基杯[4]芳烃的部分锥构象
4. Synthesis of fully O-alkylated calix4arenes in a cone conformation using a liquid-liquid phase transfer catalytic process [C] . B. Serban, C. Nechifor, M. E. Craciun, 12th Romanian International Conference on Chemistry and Chemical Engineering, Sep 13-15, 2001, Bucharest, Romania . 2001

机译：使用液相-液相转移催化方法合成呈锥构型的完全O-烷基化杯4芳烃
5. Part I. Synthesis of 1,3,3-trinitroazetidine via the oxidative nitration of N-p-tosyl-3-azetidinone oxime, and Part II. Synthesis and conformational studies of urea-based calix(4)arenes. [D] . Yazdekhasti, Hamid. 1995

机译：第一部分，通过N-对甲苯磺酰基-3-氮杂环丁酮肟的氧化硝化合成1,3,3-三硝基氮杂环丁烷，第二部分。脲基杯芳烃（4）芳烃的合成和构象研究。
6. Synthesis Physicochemical Studies Molecular Dynamics Simulations and Metal-Ion-Dependent Antiproliferative and Antiangiogenic Properties of Cone ICL670-Substituted Calix4arenes [O] . Dr. Pascal Rouge, Dr. Alexandra Dassonville-Klimpt, Dr. Christine Cézard, -1

机译：合成物理化学研究分子动力学模拟和金属离子依赖性抗增殖和锥形ICL670取代胶的抗血管性能4芳烃
7. Electrochemical study of two tris-O-substituted calix[4]arenes: 25,27-dipropoxy-26-hydroxy-28-benzoyloxycalix[4]arene(partial cone) and 25,27-dibenzyl-26-hydroxy-28-benzoyloxy-calix[4]-arene (partial cone). Electro synthesis of the corresponding calix[4]arene-monoquinones [O] . Louati, Alain, Spraula, Julien, Gabelica, Valérie, 2006

机译：两种三-O-取代杯[4]芳烃的电化学研究：25,27-二丙氧基-26-羟基-28-苯甲酰氧基杯[4]芳烃（部分锥体）和25,27-二苄基-26-羟基-28-苯甲酰氧基-calix [4] -arene（部分锥体）。相应杯[4]芳烃-单醌的电合成

Electrochemical study of two tris-O-substituted calix[4]arenes: 25,27-dipropoxy-26-hydroxy-28-benzoyloxycalix[4]arene(partial cone) and 25,27-dibenzyl-26-hydroxy-28-benzoyloxy-calix[4]-arene (partial cone). Electro synthesis of the corresponding cali

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