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首页> 外文期刊>European Journal of Glass Science and Technology, PartB. Physics and Chemistry of Glasses >Effects of substituting P2O5 for B2O3 on the thermal and optical properties of sodium borophosphate glasses doped with Er
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Effects of substituting P2O5 for B2O3 on the thermal and optical properties of sodium borophosphate glasses doped with Er

机译:用P2O5代替B2O3对掺Er硼酸钠玻璃的热学和光学性质的影响。

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摘要

In this paper a set of (95-x)P2O5-xB2O3-4·9Na2O-0·1Er2O3 (x=5, 10, 15, 20 mol%) samples was prepared using a conventional melt-quenching technique. A glass ceramic phase was confirmed by x-ray diffraction. The glass containing 20 mol% B2O3 shows a high thermal stability with a value AT=T_c-T_g exceeding 100°C, where T_g and T_c are the glass transition and crystallization onset temperatures. From the absorption edge studies, the value of the optical band gap E_(opt) has been evaluated. The fundamental absorption edge for all the glasses was analyzed and the Judd-Ofelt parameters (Ω2, Ω4 and Ω6) were obtained. The PL intensity, the PL life time and the quantum efficiency relative to the ~1I_(13/2)→~4I_(15/2) (1530 nm) transition of Er~(3+) were all found to decrease with the addition of B2O3.
机译:在本文中,使用常规的熔融淬火技术制备了一组(95-x)P2O5-xB2O3-4·9Na2O-0·1Er2O3(x = 5、10、15、20 mol%)样品。通过X射线衍射确认了玻璃陶瓷相。包含20 mol%B2O3的玻璃显示出高的热稳定性,其值AT = T_c-T_g超过100°C,其中T_g和T_c是玻璃化转变和结晶起始温度。根据吸收边缘研究,已评估了光学带隙E_(opt)的值。分析了所有眼镜的基本吸收边缘,并获得了Judd-Ofelt参数(Ω2,Ω4和Ω6)。相对于Er〜(3+)的〜1I_(13/2)→〜4I_(15/2)(1530 nm)跃迁,PL强度,PL寿命和量子效率均随着添加而降低。 B2O3。

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