Synthesis, Chemistry, and Catalytic Activity of Ruthenium Diaminodiphosphane Complexes - Crystal Structures of trans-[RuCl_2{k~3-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh_2}(PPh_3)] and cis-[RuCl_2{k~4-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh)2}]

Wai-Kwok Wong; Xiao-Ping Chen; Wei-Xiong Pan; Jian-Ping Guo; Wai-Yeung Wong

首页> 外文期刊>European journal of inorganic chemistry >Synthesis, Chemistry, and Catalytic Activity of Ruthenium Diaminodiphosphane Complexes - Crystal Structures of trans-[RuCl_2{k~3-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh_2}(PPh_3)] and cis-[RuCl_2{k~4-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh)2}]

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Synthesis, Chemistry, and Catalytic Activity of Ruthenium Diaminodiphosphane Complexes - Crystal Structures of trans-[RuCl_2{k~3-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh_2}(PPh_3)] and cis-[RuCl_2{k~4-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh)2}]

机译：钌二氨基二膦配合物的合成，化学及催化活性-反式-[RuCl_2 {k〜3-Ph_2PC_6H_4CH = NC_6H_（10）N（H）CH_2C_6H_4PPh_2}（PPh_3）]和顺式[RuCl_2 {k〜4- Ph_2PC_6H_4CH = NC_6H_（10）N（H）CH_2C_6H_4PPh）2}]

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The interaction of [RuCl_2(PPh_3)_3] with one equivalent of N,N'-bis[2-(diphenylphosphanyl)benzyl]-1R,2R-cyclo-hexanediamine [1R,2R-P(NH)(NH)_P] in dichloromethane at room temperature gave trans-[RuCl_2{k~3-1R,2R-0(NH)(NH)P}(PPh_3)] (1). When heated under reflux in toluene under a nitrogen atmosphere, 1 was converted into trans-[RuCl_2{k~4-1R,2R-P(NH)(NH)P}] (2). However, when 1 was stirred at room temperature in air, it was oxidized to trans-[RuCl_2{k~3-1R,2R-PN(NH)P}(PPh_3)] (3). Depending on the reaction conditions, 3 was converted into trans-[RuCl_2{k~3-1R,2R-P(NH)(NH)P=O}(PPh_3)] (4) when heated to 80 ℃ in toluene in air, to cis[RuCl_2{k~4-1R,2R-PN(NH))P}] (5) when stirred at room temperature in acetone in air, or to trans-[RuCl_2{k~4-1R,2R-PN(NH)P}] (6) when heated under reflux in acetone under a nitrogen atmosphere. When heated under reflux in toluene under a nitrogen atmosphere, 5 isomerized to 6 quantitatively. When heated under reflux in mesitylene under a nitrogen atmosphere, 6 was slowly reduced to 2. The solid state structures of 3 and 5 were ascertained by X-ray crystallography. Catalytic studies showed that 1 could catalyze the oxidation of alkenes and alkenes with molecular oxygen.

机译：[RuCl_2（PPh_3）_3]与一当量的N，N'-双[2-（二苯基膦基）苄基] -1R，2R-环己二胺[1R，2R-P（NH）（NH）_P]的相互作用在室温下于二氯甲烷中得到反-[RuCl_2 {k〜3-1R，2R-0（NH）（NH）P}（PPh_3）]（1）。在氮气气氛下在甲苯中加热回流时，将1转化为反式-[RuCl_2 {k〜4-1R，2R-P（NH）（NH）P}]（2）。但是，在室温下于空气中搅拌1时，其被氧化为反式-[RuCl_2 {k〜3-1R，2R-PN（NH）P}（PPh_3）]（3）。根据反应条件，在甲苯中于空气中加热到80℃时，3转化为反式[RuCl_2 {k〜3-1R，2R-P（NH）（NH）P = O}（PPh_3）]（4），在室温下于丙酮中于空气中搅拌时，顺式[RuCl_2 {k〜4-1R，2R-PN（NH））P}]（5），或反式-[RuCl_2 {k〜4-1R，2R- PN（NH）P}]（6），在氮气气氛下在丙酮中加热回流。在氮气气氛下在甲苯中加热回流时，将5异构化为6。在氮气氛下在1，3，5-三甲苯中在回流下加热时，将6缓慢还原为2。通过X射线晶体学确定3和5的固态结构。催化研究表明1可以催化烯烃和烯烃与分子氧的氧化。

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《European journal of inorganic chemistry》 |2002年第1期|共7页
作者
Wai-Kwok Wong; Xiao-Ping Chen; Wei-Xiong Pan; Jian-Ping Guo; Wai-Yeung Wong;
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正文语种 eng
中图分类无机化学;
关键词
ruthenium; N; P ligands; catalysis; oxidations;

机译：钌;N;P配体;催化;氧化;

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1. Synthesis, Chemistry, and Catalytic Activity of Ruthenium Diaminodiphosphane Complexes - Crystal Structures of trans-[RuCl_2{k~3-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh_2}(PPh_3)] and cis-[RuCl_2{k~4-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh)2}] [J] . Wai-Kwok Wong, Xiao-Ping Chen, Wei-Xiong Pan, European journal of inorganic chemistry . 2002,第1期

机译：钌二氨基二膦配合物的合成，化学及催化活性-反式-[RuCl_2 {k〜3-Ph_2PC_6H_4CH = NC_6H_（10）N（H）CH_2C_6H_4PPh_2}（PPh_3）]和顺式[RuCl_2 {k〜4- Ph_2PC_6H_4CH = NC_6H_（10）N（H）CH_2C_6H_4PPh）2}]
2. ~(31)P{~1H}-n.m.r.as a tool for identification of ruthenium isomers containing PPh_3 or l,4-bis(diphenylphosphino)butane ligands.X-ray structures of the cis-{RuCl_2 (PPh_3)_2 I4,4'-(-X)_2-2,2'-bipy]} complexes [X =-H,-Me,-SMe and (-C1,-Me)] [J] . Marcelo O.Santiago, Alzir A.Batista, Marcio P.de Araujo, Transition Metal Chemistry . 2005,第2期

机译：〜（31）P {〜1H} -nmras-用于鉴定含有PPh_3或1,4-双（二苯基膦基）丁烷配体的钌异构体的工具。顺式-{RuCl_2（PPh_3）_2 I4,4的X射线结构'-（-X）_2-2,2'-bipy]}复合物[X = -H，-Me，-SMe和（-C1，-Me）]
3. New routes to carbonyl complexes of general formula [RuCl_2(CO)(S)(PPh_3)_2](S=DMA,DMF,DMSO): crystal structure of [RuCl_2(CO)(DMA)(PPh_3)_2].1/2CH_2Cl_2 [J] . Alzir A.Batista, Karen Wonrath, Salete L.Queiroz, Transition Metal Chemistry . 2001,第3期

机译：通式为[RuCl_2（CO）（S）（PPh_3）_2]（S = DMA，DMF，DMSO）的羰基配合物的新路线：[RuCl_2（CO）（DMA）（PPh_3）_2] .1 / 1的晶体结构2CH_2Cl_2
4. Synthesis and Structures of Ruthenium Carbonyl Complexes Bearing Pyridine-Alkoxide Ligands and Their Catalytic Activity in Alcohol Oxidation [O] . Xinlong Yan, Xiaohui Yue, Kang Liu, 1970

机译：含吡啶-烷氧基配体的钌羰基配合物的合成，结构及其在醇氧化中的催化活性
5. Copper(I) complexes with 5-(allylthio)-1H-tetrazoles: synthesis and crystal structure of Cu2(C10H10N4S)2(H2O)2(BF4)2 and Cu2(C10H9ClN4S)2(H2O)2(BF4)2·C2H5OH π-compounds (C10H10N4S and C10H9ClN4S - 5-(allylthio)-1-phenyl- and 5-(allylthio)-1-(4-chlorophenyl)-1H-tetrazole) [O] . Yuriy SLYVKA, Nazariy POKHODYLO, Roman SAVKA, 2010

机译：铜（I）配合物，具有5-（烯丙基硫基）-1H-四唑：Cu 2（C10H10N4S）2（H 2 O）2（BF4）2和Cu 2（C10H9ClN 4）2（H2O）2的合成和晶体结构（BF4 ）2·C 2 H 5 OHπ-化合物（C10H10N4S和C10H9CLN4S - 5-（烯丙基硫基）-1-苯基 - 和5-（烯丙基）-1-（4-氯苯基）-1H-四唑）
6. Synthesis of nido- and closo-diplatinacarborane Complexes by Direct Insertion; Crystal and Molecular Structures of closo-2-3-((Et3P)2)2-1-2-3-6-CPt2CB5H7-nido-4-8-((Me3P)2Pt)-8- 8((Me3P)2)-7-8-10-CPtCB8H10 and nido-8-8-((Me3P)2)-7-8-10-CPtCB8H10. [R] . Barker, G. K., Green, M., Spencer, J. L., 1975

机译：直接插入法合成nido-和closo-diplatinacarborane配合物; closo-2-3 - （（Et3p）2）2-1-2-3-6-Cpt2CB5H7-nido-4-8 - （（me3p）2pt）-8-8（（me3p）2的晶体和分子结构）-7-8-10-CptCB8H10和nido-8-8 - （（me3p）2）-7-8-10-CptCB8H10。

Synthesis, Chemistry, and Catalytic Activity of Ruthenium Diaminodiphosphane Complexes - Crystal Structures of trans-[RuCl_2{k~3-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh_2}(PPh_3)] and cis-[RuCl_2{k~4-Ph_2PC_6H_4CH=NC_6H_(10)N(H)CH_2C_6H_4PPh)2}]

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