The influence of ring size on the selectivity of phosphorus heterocycle aminolysis in the presence of water or alcohols - Case of 2-oxo- or 2-thioxo-3-sulfonyl-1,3,2-oxazaphosphorinanes

Dujols F; Mulliez M

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The influence of ring size on the selectivity of phosphorus heterocycle aminolysis in the presence of water or alcohols - Case of 2-oxo- or 2-thioxo-3-sulfonyl-1,3,2-oxazaphosphorinanes

机译：在水或醇存在下，环的大小对磷杂环氨解选择性的影响-2-氧代或2-硫代-3-磺酰基-1,3,2-氧杂氮磷杂环丁烷的情况

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Seven phosphorus heterocycles 2 were synthesized in one step by condensing P-IV dichlorides 3 with N-sulfonyl-3-aminopropanols 4. In the presence of water, they react selectively with the less bulky amines. No change in selectivity of aminolysis was observed when using these six-membered heterocycles 2 instead of their five-membered analogs 1. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

机译：通过将P-IV二氯化物3与N-磺酰基-3-氨基丙醇4缩合，一步合成了七个磷杂环2。在水的存在下，它们与体积较小的胺选择性地反应。当使用这些六元杂环2而不是其五元类似物1时，未观察到氨解选择性的变化。（（c）Wiley-VCH Verlag GmbH＆Co.KGaA，69451 Weinheim，德国，2006）。

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《European journal of organic chemistry》 |2006年第8期|共6页
作者
Dujols F; Mulliez M;
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正文语种 eng
中图分类有机化学;
关键词
amino alcohols; sulfonamides; phosphorus heterocycles; phosphorylation; chemoselectivity; INTRAMOLECULAR CATALYSIS; MOIETY; DERIVATIVES; ACIDS; SULFONAMIDES; REACTIVITY; RESIDUE; AMINES;

机译：氨基醇;磺酰胺;磷杂环;磷酸化;化学选择性;分子内催化;部分;衍生物;酸;磺酰胺;反应性;残基;胺;

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1. The influence of ring size on the selectivity of phosphorus heterocycle aminolysis in the presence of water or alcohols - Case of 2-oxo- or 2-thioxo-3-sulfonyl-1,3,2-oxazaphosphorinanes [J] . Dujols F, Mulliez M European journal of organic chemistry . 2006,第8期

机译：在水或醇存在下，环的大小对磷杂环氨解选择性的影响-2-氧代或2-硫代-3-磺酰基-1,3,2-氧杂氮磷杂环丁烷的情况
2. Intramolecualr Catalysis of Aminolysis of Phosphorus Heterocycles Incorporating an #alpha#-aminoamide Moiety. III. synthesis of 2-Oxo or 2-Thioxo 1,3-disulfonyl-1,3,2-diazaphospholidines and Reactions with Amines and Alcohols [J] . Frederic J.M.Dujols, Michel E.Mulliez Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2001,第2期

机译：掺入＃α＃-氨基酰胺基团的磷杂环酰胺分解的分子内催化。三， 2-Oxo或2-Thioxo 1,3-二磺酰基-1,3,2-二氮磷吡啶的合成以及与胺和醇的反应
3. C-3 selective ring opening of 2,3-aziridino alcohols and their derivatives with nucleophiles in the presence of beta-cyclodextrin in water [J] . Krishnaveni NS, Surendra K, Rao KR Advanced synthesis & catalysis . 2006,第6期

机译：在水中存在β-环糊精的情况下2,3-叠氮基醇及其衍生物与亲核试剂的C-3选择性开环
4. Selective Sensing of Alcohols in Water Influenced by Zeolite Coatings on Optical Fiber [C] . Marziyeh Nazari, Matthew R. Hill, Mikel Duke, International Conference on Optical Fibre Sensors . 2014

机译：光纤上沸石涂层对水中酒精的选择性感测
5. Ring-closingmetathesis to phosphorus heterocycles: Application to DMP 323 analogues and related studies [D] . McReynolds, Matthew David 2004

机译：磷杂环开环置换：在DMP 323类似物和相关研究中的应用
6. Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum–nitrogen heterocycles [O] . Regina Drescher, Shujuan Lin, Alexander Hofmann, 2020

机译：用有机叠氮的糖膨胀：选择性地形成六元铝 - 氮杂环
7. Selective and Sequential Aminolysis of Benzotrifuranone: Synergism of Electronic Effects and Ring Strain Gradient [O] . -1

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8. Evaluation of Operating Parameters of Alumina Columns for the Selective Removal of Phosphorus from Waste-Waters and the Ultimate Disposal of Phosphorus as Calcium Phosphate [R] . Ames, L. L. 1969

机译：氧化铝柱选择性去除废水中磷的操作参数评价及磷酸钙的最终处理

The influence of ring size on the selectivity of phosphorus heterocycle aminolysis in the presence of water or alcohols - Case of 2-oxo- or 2-thioxo-3-sulfonyl-1,3,2-oxazaphosphorinanes

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