The First Synthesis of Dually Modified Southern-Mimicking Nucleoside:4'-Methyl Branched and Bicyclo [3.1.0] Hexane Locked Nucleoside

Kwan Woo Kim; Joon Hee Hong

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The First Synthesis of Dually Modified Southern-Mimicking Nucleoside:4'-Methyl Branched and Bicyclo [3.1.0] Hexane Locked Nucleoside

机译：双重修饰的拟南芥核苷的首次合成：4'-甲基支链双环[3.1.0]己烷锁定的核苷

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摘要

This paper reports the stereoselective synthesis of a novel nucleoside,4'-methyl branched and bicyclo [3.1 0] hexane locked-nucleoside 12,using a sequential [3,3]-sigmatropic rearrangement/carbene cyclo addition reaction/Curtius reaction strategy with a high stereoselectivity.

机译：本文报告了一种立体选择性合成新型核苷，4'-甲基支链和双环[3.1 0]己烷锁定核苷12的方法，采用顺序的[3,3]-σ重排/卡宾环加成反应/ Curtius反应策略进行，高立体选择性。

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《Bulletin of the Korean Chemical Society》 |2004年第5期|共5页
作者
Kwan Woo Kim; Joon Hee Hong;
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正文语种 eng
中图分类化学工业;
关键词
ocked-nucleoside; 3; 3-sigmatropic rearrangement; Curtius reaction; Antiviral agents;

机译：核苷;[3;3]-σ重排;Curtius反应;抗病毒药;

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专利

1. The First Synthesis of Dually Modified Southern-Mimicking Nucleoside:4'-Methyl Branched and Bicyclo [3.1.0] Hexane Locked Nucleoside [J] . Kwan Woo Kim, Joon Hee Hong Bulletin of the Korean Chemical Society . 2004,第5期

机译：双重修饰的拟南芥核苷的首次合成：4'-甲基支链双环[3.1.0]己烷锁定的核苷
2. Synthesis of conformationally locked l-deoxythreosyl phosphonate nucleosides built on a bicyclo[3.1.0]hexane template [J] . Saneyoshi H., Deschamps J.R., Marquez V.E. The Journal of Organic Chemistry . 2010,第22期

机译：在双环[3.1.0]己烷模板上构建构象锁定的l-脱氧苏糖基膦酸酯核苷
3. Stereoselective synthesis of novel 4'-branched and bicyclo(3.1.0)hexane-templated nucleoside. [J] . Hong JH Nucleosides, nucleotides and nucleic acids . 2004,第3期

机译：立体选择性合成新型4'-支链和双环（3.1.0）己烷为模板的核苷。
4. Mass spectral analysis of modified nucleosides and nucleoside monophosphates [C] . Kirk W. Gaston, Patrick A. Limbach American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2013

机译：改性核苷和核苷单磷酸核苷的质谱分析
5. REACTIVE INTERMEDIATES IN THE BICYCLO(3.1.0)HEXANE AND TRICYCLO(3.2.1.0(2,4))OCTANE RING SYSTEMS. [D] . KUPER, DONALD GRAHAM. 1966

机译：双环（3.1.0）己烷和三环（3.2.1.0（2,4））辛烷环系统中的反应中间体。
6. Synthesis of Conformationally North-Locked Pyrimidine Nucleosides Built on an Oxa-bicyclo3.1.0hexane Scaffold [O] . Olaf R. Ludek, Victor E. Marquez -1

机译：建立在一个杂 - 双环构象北锁定嘧啶核苷的合成3.1.0己烷脚手架
7. The First Synthesis of Dually Modified Southern-Mimicking Nucleoside: 4'-Methyl Branched and Bicyclo 3.1.0 Hexane Locked Nucleoside [O] . 2004

机译：第一次合成双重修饰的南部模拟核苷：4'-甲基支链和双环3.1.0己烷锁定核苷

The First Synthesis of Dually Modified Southern-Mimicking Nucleoside:4'-Methyl Branched and Bicyclo [3.1.0] Hexane Locked Nucleoside

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