Synthesis and Structure of the New Fe complex,[Fe~(II)Cl_3(PEt_3)]~-

Jaehong Han; Wonwoo Nam

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Synthesis and Structure of the New Fe complex,[Fe~(II)Cl_3(PEt_3)]~-

机译：新型Fe络合物[Fe〜（II）Cl_3（PEt_3）]〜-的合成与结构

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Reduced simple Fe salt has played an important role in the synthesis of high nuclearity transition metal clusters.Especially trialkylphosphine ligand-containing Fe compounds,such as FeCl_2(PEt_3)_2,have been valuable starting materials in the synthesis of model compounds of nitrogenase cofactor (MoFe_7S_9X).The dissociation of trialkylphosphine opens up vacant coordination sites around the Fe atom to build high nuclearity clusters.At the same time,the dissociated trialkylphosphine can act as an additional ligand for the product and as a weak reducing reagent in the reaction.On the line of this logic,a new phosphine-containing monometallic Fe reagent,(Et_4N)[FeCl_3(PEt_3)] was synthesized.

机译：还原的简单Fe盐在合成高核过渡金属簇中起着重要作用。特别是含三烷基膦配体的Fe化合物，例如FeCl_2（PEt_3）_2，已经成为合成固氮酶辅因子模型化合物的有价值的起始原料（ MoFe_7S_9X）。三烷基膦的解离打开了Fe原子周围的空位配位位点，以建立高核簇。同时，离解的三烷基膦可作为产物的附加配体和反应中的弱还原剂。根据这一逻辑，合成了一种新的含膦单金属铁试剂（Et_4N）[FeCl_3（PEt_3）]。

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《Bulletin of the Korean Chemical Society》 |2004年第6期|共3页
作者
Jaehong Han; Wonwoo Nam;
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正文语种 eng
中图分类化学工业;
关键词
synthesis; high-spin ferrous compounds; FeCl_2; x-ray structure; mossbauer;

机译：合成;高自旋含铁化合物;FeCl_2;x射线结构;mossbauer;

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Synthesis and Structure of the New Fe complex,[Fe~(II)Cl_3(PEt_3)]~-

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