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A Kinetic Consideration on the Selective Adsorption and Molecular Recognition by Molecularly Imprinted Polymer

机译:分子印迹聚合物选择性吸附和分子识别的动力学考虑

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摘要

This article presents an original work on kinetically studying the selective adsorption and recognition by molecularly imprinted polymer (MIP).With S-naproxen as template,the imprinted polymer was prepared.The result indicates that the prepared polymer shows a more complicated sorption toward S-naproxen than toward its enantiomer R-naproxen.The rate constant in the case of template appears to be a variable.There are also significant deviations from the idealized Langmuir model.Related information indicates that these,in logic,can be a result of biomimic structural and functional complements between imprint and the template,which makes the polymer capable of selectively recognizing the imprint species.
机译:本文以分子印迹聚合物(MIP)为研究对象,对其动力学进行了初步研究。以S-萘普生为模板制备了印迹聚合物,结果表明所制备的聚合物对S-萘酚的吸附更为复杂。在模板的情况下,速率常数似乎是一个变量。与理想的朗缪尔模型也存在显着偏差。相关信息表明,从逻辑上讲,这些可能是仿生结构的结果印迹和模板之间的功能互补,使得聚合物能够选择性地识别印迹种类。

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