Study on reactions of long-lived phenoxathiin radical cation with aliphatic alcohols, phenol and phenyl halides in ambient condition by fused-droplet electrospray ionization mass spectrometry

Yao S.-J.; Wang H.-Y.; Zhang L.; Zhang J.; Guo Y.-L.

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Study on reactions of long-lived phenoxathiin radical cation with aliphatic alcohols, phenol and phenyl halides in ambient condition by fused-droplet electrospray ionization mass spectrometry

机译：熔滴电喷雾电离质谱法研究环境中长寿命酚氧磷酯自由基阳离子与脂肪醇，苯酚和苯基卤化物的反应

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The reactions of phenoxathiin radical cations with diverse organic compounds in ambient conditions were realized by using fused-droplet electrospray ionization mass spectrometry. In the investigation, the phenoxathiin radical cation was prepared by electrospray ionization. The reactants included aliphatic alcohols, phenol and phenyl halides and the reaction studies showed the unique reactivity the of phenoxathiin radical cation towards neutral organic compounds in ambient conditions, which has not been revealed in previous studies.

机译：通过使用熔融液滴电喷雾电离质谱法实现了在环境条件下苯恶硫磷自由基阳离子与各种有机化合物的反应。在研究中，通过电喷雾电离制备了苯氧噻啶自由基阳离子。反应物包括脂族醇，苯酚和卤代苯，反应研究表明，在环境条件下，苯氧噻啶自由基阳离子对中性有机化合物具有独特的反应性，这在先前的研究中尚未得到揭示。

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《European journal of mass spectrometry》 |2011年第4期|共10页
作者
Yao S.-J.; Wang H.-Y.; Zhang L.; Zhang J.; Guo Y.-L.;
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正文语种 eng
中图分类质谱分析;
关键词
FD-ESI; Phenoxathiin radical cation; Radical chemistry; Reactivity investigation;

机译：FD-ESI;苯氧ath啶自由基阳离子;自由基化学;反应性研究;

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1. Study on reactions of long-lived phenoxathiin radical cation with aliphatic alcohols, phenol and phenyl halides in ambient condition by fused-droplet electrospray ionization mass spectrometry [J] . Yao S.-J., Wang H.-Y., Zhang L., European journal of mass spectrometry . 2011,第4期

机译：熔滴电喷雾电离质谱法研究环境中长寿命酚氧磷酯自由基阳离子与脂肪醇，苯酚和苯基卤化物的反应
2. Investigation of Reactive Intermediates of Chemical Reactions in Solution by Electrospray Ionization Mass Spectrometry: Radical Cation Chain Reactions [J] . Sven Meyer, Rainer Koch, Jurgen O. Metzger Angewandte Chemie . 2003,第38期

机译：电喷雾电离质谱研究溶液中化学反应的反应中间体：自由基阳离子链反应
3. Detection of transient radical cations in electron transfer-initiated Diels-Alder reactions by electrospray ionization mass spectrometry [J] . Furmeier S, Metzger JO Journal of the American Chemical Society . 2004,第44期

机译：电喷雾电离质谱法检测电子转移引发的Diels-Alder反应中的瞬态自由基阳离子
4. The Development of Quantitative Real-Time Detection of Flavors During Fermentation by Fused-Droplet Electrospray Ionization (FD-ESI) Mass Spectrometry [C] . Chang-Nan Chen, Jentai Shiea, Yi-Feng Lin, ASMS Conference on Mass Spectrometry and Allied Topics . 2008

机译：通过熔融液滴电喷雾电离（FD-ESI）质谱法在发酵过程中的定量实时检测的发展
5. High spatial resolution chemical imaging and accelerated bimolecular reactions using ambient ionization mass spectrometry: Desorption electrospray ionization (DESI) and low temperature plasma (LTP) ionization. [D] . Campbell, Dahlia I. 2012

机译：使用环境电离质谱技术的高空间分辨率化学成像和加速的双分子反应：解吸电喷雾电离（DESI）和低温等离子体（LTP）电离。
6. Identification and Quantification of Flavonoids and Phenolic Acids in Burr Parsley (Caucalis platycarpos L.) Using High-Performance Liquid Chromatography with Diode Array Detection and Electrospray Ionization Mass Spectrometry [O] . Ana Plazonić, Franz Bucar, Željan Maleš, 2009

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7. Detection of Transient Radical Cations in Electron Transfer-Initiated Diels-Alder Reactions by Electrospray Ionization Mass Spectrometry [O] . -1

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机译：利用多位点聚合酶链反应/电喷雾电离质谱鉴定细菌植物病原菌

Study on reactions of long-lived phenoxathiin radical cation with aliphatic alcohols, phenol and phenyl halides in ambient condition by fused-droplet electrospray ionization mass spectrometry

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