Efficient clustering of cyclic sulphonium salts applying liquid secondary ion mass spectrometry

Cozzolino R; Gallagher RT; Drewello T

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Efficient clustering of cyclic sulphonium salts applying liquid secondary ion mass spectrometry

机译：应用液体二次离子质谱法对环sulph盐进行高效聚类

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Salt-like cluster ions of the ([cation](n)[anion](n-1))(+) type are commonly composed of mono-atomic, inorganic components. Clusters containing organic ions are also known, with nitrogen - centred cations being particularly prominent. However, sulphur-centred analogues, such as organic sulphonium salts, represent a notable exception. Fast atom bombardment and liquid secondary ion mass spectrometry of such compounds show, in general, a low tendency towards the formation of clusters. The present study reveals that sputtering of cyclic sulphonium salts leads to the efficient formation of cluster ions beyond previous observations. Cluster ions are characterised by isotopic pattern analysis and collision-induced dissociation.

机译：（[阳离子]（n）[阴离子]（n-1））（+）型的类盐簇离子通常由单原子的无机成分组成。包含有机离子的簇也是已知的，其中以氮为中心的阳离子尤其突出。然而，以硫为中心的类似物，例如有机sulph盐，是一个明显的例外。通常，此类化合物的快速原子轰击和液体二次离子质谱显示出形成簇的趋势较低。本研究揭示了环sulph盐的溅射导致簇离子的有效形成，超出了先前的观察范围。团簇离子的特征在于同位素模式分析和碰撞诱导解离。

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《European journal of mass spectrometry》 |2006年第1期|共5页
作者
Cozzolino R; Gallagher RT; Drewello T;
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正文语种 eng
中图分类分析化学;
关键词
cyclic sulphonium salt clusters; sulphonium ion; cluster formation; liquid secondary ion mass spectrometry; DYNAMICS; CHLORIDE; SPECTRA; SODIUM;

机译：环状sulph盐簇;s离子;团簇形成;液相二次离子质谱;动力学;氯离子;光谱;钠;

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1. Efficient clustering of cyclic sulphonium salts applying liquid secondary ion mass spectrometry [J] . Cozzolino R, Gallagher RT, Drewello T European journal of mass spectrometry . 2006,第1期

机译：应用液体二次离子质谱法对环sulph盐进行高效聚类
2. Effects of liquid phase composition on salt cluster formation in positive ion mode electrospray mass spectrometry: Implications for clustering mechanism in electrospray [J] . Charles L., Gonnet F., Tabet FC., Journal of the American Society for Mass Spectrometry . 2001,第10期

机译：液相模式对正离子模式电喷雾质谱中盐簇形成的影响：对电喷雾成簇机理的启示
3. Cluster secondary ion mass spectrometry imaging of interfacial reactions of TiO2 microspheres embedded in ionic liquids [J] . Shen Kan, Tarolli Jay G., Winograd Nicholas Rapid Communications in Mass Spectrometry: RCM . 2016,第3期

机译：嵌入离子液体中的TiO2微球界面反应的簇次离子质谱成像
4. A new liquid-type cluster-ion-beam source for Secondary Ion Mass Spectrometry using an electrospray ionization technique [C] . Yukio Fujiwara, Kouji Watanabe, Hidehiko Nonaka, ASMS Conference on Mass Spectrometry and Allied Topics . 2008

机译：用于二次离子质谱法的新型液体型簇离子束源使用电喷雾电离技术
5. Applying secondary ion mass spectrometry to cellular and model membranes to image component distribution and quantify composition [D] . Wilson, Robert Lloyd. 2012

机译：将二次离子质谱法施加到细胞和模型膜上的图像成分分布和量化组合物
6. Correlative mass spectrometry imaging applying time‐of‐flight secondary ion mass spectrometry and atmospheric pressure matrix‐assisted laser desorption/ionization to a single tissue section [O] . N. Desbenoit, A. Walch, B. Spengler, -1

机译：相关质谱成像将飞行时间二次离子质谱和大气压基质辅助的激光解吸/电离应用于单个组织切片
7. Effects of liquid phase composition on salt cluster formation in positive ion mode electrospray mass spectrometry: implications for clustering mechanism in electrospray [O] . Charles Laurence, Pépin Denise, Gonnet Florence, 2001

机译：液相组成对正离子模式电喷雾质谱法中盐簇形成的影响：对电喷雾成簇机理的影响
8. Structural Characterization of Reactive Dyes Using Liquid Secondary Ion Mass Spectrometry/Tandem Mass Spectrometry [R] . Richardson, S. D., Thruston, A. D., McGuire, J. M., 1993

机译：液相二次离子质谱/串联质谱法研究活性染料的结构表征

Efficient clustering of cyclic sulphonium salts applying liquid secondary ion mass spectrometry

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