The role of the oxygen molecule in the photolysis of fullerenes

Juha L.; Hamplova V.; Kodymova J.; Mullerova A.; Krasa J. Laska L.; Spalek O.; Kubat P.; Stibor I.; Koudoumas E.; Couris S.; Farnikova M.

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The role of the oxygen molecule in the photolysis of fullerenes

机译：氧分子在富勒烯光解中的作用

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Experiments designed to clarify the role of molecular oxygen in the photolysis of fullerene are described. The formation of oxygen-fullerene adducts, both in fullerene solutions in various solvents and in micro-crystallites formed by evaporating these solutions, and their photolysis was studied under various experimental conditions. The results confirm that the role of oxygen in the photolysis process in these systems is ambivalent and highly dependent on the conditions under which the irradiation of the fullerenes occurs (wavelength and intensity of the photolyzing radiation, character of the solvent molecules, presence of additional molecules in the solvent-fullerene-oxygen system, etc.). [References: 52]

机译：描述了旨在阐明分子氧在富勒烯光解中的作用的实验。在各种溶剂中的富勒烯溶液中以及通过蒸发这些溶液而形成的微晶中，氧-富勒烯加合物的形成均在各种实验条件下进行了研究。结果证实，氧气在这些系统中的光解过程中的作用是矛盾的，并且高度依赖于富勒烯辐照发生的条件（光解辐射的波长和强度，溶剂分子的特性，其他分子的存在）在溶剂-富勒烯-氧气系统等中）。 [参考：52]

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《Fullerene science and technology》 |2000年第5期|共30页
作者
Juha L.; Hamplova V.; Kodymova J.; Mullerova A.; Krasa J. Laska L.; Spalek O.; Kubat P.; Stibor I.; Koudoumas E.; Couris S.; Farnikova M.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Solid c-60 films; Singlet-oxygen; Photoinduced polymerization; Photophysical properties; Induced oxidation; C-70 fullerenes; C60; Mechanism; Spectroscopy; Degradation;

机译：固态c-60膜;单氧;光致聚合;光物理性质;诱导氧化;C-70富勒烯;C60;机理;光谱学;降解;

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1. The role of the oxygen molecule in the photolysis of fullerenes [J] . Juha L., Hamplova V., Kodymova J., Fullerene science and technology . 2000,第4a5期

机译：氧分子在富勒烯光解中的作用
2. Optical Oxygen Pressure Sensing Based on Triplet-Triplet Quenching of Fullerene-Polystyrene Film Using Laser Flash Photolysis: Soccerballene C_(60) Versus Rugbyballene C_(70) [J] . Yutaka Amao, Keisuke Asai, Ichiro Okura Bulletin of the Chemical Society of Japan . 1999,第10期

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3. The Role of the Hydrogen Bond between Piperazine and Fullerene Molecules in Stabilizing Polymer:Fullerene Solar Cell Performance [J] . Li Zerui, Shan Jiankai, Yan Lingpeng, ACS applied materials & interfaces . 2020,第13期

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4. The fullerene-oxygen-iodine laser. Problem of scaling of the singlet oxygen generator with optically pumped fullerene [C] . Danilov O.B., Bagrov I.V., Belousova I.M., International Symposium on Gas Flow, Chemical Lasers, and High-Power Lasers pt.1 . 2007

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6. Photostabilityof Fullerene and Non-Fullerene PolymerSolar Cells: The Role of the Acceptor [O] . Nutifafa Y. Doumon, *, Mikhail V. Dryzhov, -1

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7. Regioselective Oxygenative Tetraamination of 60Fullerene. Fullerene-mediated Reduction of Molecular Oxygen by Amine via Ground State Single Electron Transfer in Dimethyl Sulfoxide [O] . -1

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The role of the oxygen molecule in the photolysis of fullerenes

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