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首页> 外文期刊>Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation >Preparation of reactive composite latexes by 'living' radical polymerization using the RAFT process. A new class of polymer materials
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Preparation of reactive composite latexes by 'living' radical polymerization using the RAFT process. A new class of polymer materials

机译:使用RAFT工艺通过“活性”自由基聚合制备反应性复合胶乳。新型高分子材料

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Communication: A new class of polymer (nanocomposite) materials of di- and triblock polymers of polystyrene, poly(butyl acrylate) and poly(acetoacetoxyethyl methacrylate) with a core-shell particle morphology and controlled molecular weight distribution were prepared via emulsion polymerization in the presence of a reversible addition/fragmentation chain transfer agent. The film properties of these blocks are far superior to the conventional blend of the two polymers even after crosslinking with 1,6-hexadiamine. [References: 16]
机译:信息交流:通过乳液聚合,在聚苯乙烯,聚(丙烯酸丁酯)和聚(乙酰乙酰氧基乙基甲基丙烯酸甲酯)的二嵌段和三嵌段聚合物中制备了具有核-壳颗粒形态和可控分子量分布的新型聚合物(纳米复合材料)。可逆加成/断裂链转移剂的存在。这些嵌段的膜性质甚至在与1,6-己二胺交联之后也远远优于两种聚合物的常规共混物。 [参考:16]

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