Preparation of Polymer Nanocomposite Materials by 'Living' Radical Polymerization Using the RAFT Process

机译：利用筏法制备“生活”自由基聚合制备聚合物纳米复合材料

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Adopting the reversible addition-fragmentation chain transfer (RAFT) technique to emulsion polymerization has been a long standing focus of our group. Although RAFT polymerization is relatively straightforward in solution and bulk for the "highly" active RAFT agents such as dithioesters, RAFT-derived polymers have proven difficult to control via classical ab initio (i.e. where surfactant micelles are used as mircoreactors for polymerization) and seeded (where prepolymer particles are used as the microreactors) emulsion polymerizations1.

机译：采用可逆添加 - 碎片链转移（RAFT）技术至乳液聚合是我们组的长期焦点。虽然筏聚合在溶液中相对简单，但是对于“高度”的“高度”的活性筏剂如二硫代体，筏衍生的聚合物已经证明难以通过经典的AB初始（即，所述表面活性剂胶束用作聚合的MircoreActors）和种子（其中预聚物颗粒用作微反应器）乳液聚合体1。

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《Division of Polymeric Material: Science and Engineering American Chemical Society meeting》|2004年||共2页
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Michael J. Monteiro; Wilfred Smulders;
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中图分类高分子化合物工业（高聚物工业）;
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1. Preparation of reactive composite latexes by 'living' radical polymerization using the RAFT process. A new class of polymer materials [J] . Monteiro MJ., de Barbeyrac J. Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation . 2002,第5a6期

机译：使用RAFT工艺通过“活性”自由基聚合制备反应性复合胶乳。新型高分子材料
2. Polyolefin graft copolymers via living polymerization techniques: Preparation of poly(n-butyl acrylate)-graft-polyethylene through the combination of Pd-mediated living olefin polymerization and atom transfer radical polymerization [J] . Hong SC., Jia S., Teodorescu M., Journal of Polymer Science, Part A. Polymer Chemistry . 2002,第16期

机译：通过活性聚合技术的聚烯烃接枝共聚物：通过Pd介导的活性烯烃聚合和原子转移自由基聚合的组合制备聚丙烯酸正丁酯-接枝聚乙烯
3. Preparation of new diblock polymeric materials with carbazole groups derived from the combination of living ring-opening metathesis polymerization and atom transfer radical polymerization [J] . Der-Jang Liaw, Ching-Cheng Huang Polymer Preprints . 2003,第1期

机译：活开环易位聚合与原子转移自由基聚合相结合制备具有咔唑基团的新型二嵌段聚合物
4. Preparation of Polymer Nanocomposite Materials by "Living" Radical Polymerization Using the RAFT Process [C] . Michael J. Monteiro, Wilfred Smulders Division of Polymeric Material: Science and Engineering American Chemical Society meeting . 2004

机译：利用筏法制备“生活”自由基聚合制备聚合物纳米复合材料
5. Surface modification through atom transfer radical polymerization grafting for the preparation of protein-resistant materials. [D] . Feng, Wei. 2007

机译：通过原子转移自由基聚合接枝进行表面改性，以制备抗蛋白质材料。
6. Partial Discharge Characteristics of Polymer Nanocomposite Materials in Electrical Insulation: A Review of Sample Preparation Techniques Analysis Methods Potential Applications and Future Trends [O] . Wan Akmal Izzati, Yanuar Z. Arief, Zuraimy Adzis, -1

机译：聚合物纳米复合材料在电绝缘中的局部放电特性：样品制备技术分析方法潜在应用和未来趋势的综述
7. Well-Defined, High-Density Polymer Brushes Synthesized by Living Radical Polymerization / A Kinetic Study on Dithioester-Mediated Living Radical Polymerization of Styrene (ORGANIC MATERIALS CHEMISTRY - Polymeric Materials) [O] . FUKUDA Takeshi, TSUJI Yoshinobu, MURAKAMI Syozo, 2002

机译：通过活性自由基聚合合成的精细定义的高密度聚合物刷/二硫酯介导的苯乙烯活性自由基聚合的动力学研究（有机材料化学-高分子材料）
8. Living/Controlled Radical Polymerization. Transition-Metal-Catalyzed AtomTransfer Radical Polymerization in the Presence of a Conventional Radical Initiator [R] . Wang, J. S., Matyjaszewski, K. 1995

机译：活性/可控自由基聚合。在常规自由基引发剂存在下的过渡金属催化的原子转移自由基聚合

Preparation of Polymer Nanocomposite Materials by 'Living' Radical Polymerization Using the RAFT Process

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