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Modeling Studies of the Phase Behavior of Monomer/Polymer/Disk Composites

机译:单体/聚合物/盘状复合材料相行为的模型研究

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摘要

The model developed by Balazs et al. to explain the phase behavior of polymer/clay composites is extended to monomer/polymer/clay composites, obtaining an expression for the free energy of a monomer/polymer/thin-disk mixture. By minimizing the free energy and calculating the chemical potentials of the three system components, phase diagrams for the monomer/disk and monomer/polymer/disk mixtures are contructed. Through the evolution and comparison of these diagrams, the effects of nanodisk size, polymer molecular mass and interaction parameters (temperature) on mixture stability and attained morphology are then studied.
机译:Balazs等人开发的模型。为解释聚合物/粘土复合材料的相行为,将其扩展到单体/聚合物/粘土复合材料,获得了单体/聚合物/薄盘混合物的自由能表达式。通过最小化自由能并计算这三个系统组分的化学势,可以绘制出单体/圆盘和单体/聚合物/圆盘混合物的相图。通过这些图的演变和比较,然后研究了纳米盘尺寸,聚合物分子质量和相互作用参数(温度)对混合物稳定性和获得的形态的影响。

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