Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)

Seck G.A.; Diop L.; Oliver A.G.

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Crystal structure of the monoclinic phase (phase IV) of bis(tetramethylammonium) tetrachloridocuprate(II)

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The crystal structure of the low-temperature monoclinic phase of the title compound, (CH3)4N2CuCl4, was determined at 120 K. The structure of the room-temperature phase has been determined in the orthorhombic space group Pmcm Morosin Lingafelter (1961). J. Phys. Chem. 50–51; Clay et al. (1975). Acta Cryst. B31 289–290. The asymmetric unit consists of one discrete tetrachloridocuprate anion with a distorted tetrahedral geometry and two tetramethylammonium cations. In the crystal, the cations and the anions are linked via weak C—H⋯Cl hydrogen bonds.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第3期|358-360|共3页
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Seck G.A.; Diop L.; Oliver A.G.;
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Crystal structure of the monoclinic phase (phase IV) of bis­(tetra­methyl­ammonium) tetra­chlorido­cuprate(II)

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Crystal structure of the monoclinic phase (phase IV) of bis(tetramethylammonium) tetrachloridocuprate(II)