Synthesis, spectroscopic characterization, and observation of massive metal-insulator transitions in nanowires of a nonstoichiometric vanadium oxide bronze

Patridge C.J.; Wu T.-L.; Jaye C.; Ravel B.; Takeuchi E.S.; Fischer D.A.; Sambandamurthy G.; Banerjee S.

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Synthesis, spectroscopic characterization, and observation of massive metal-insulator transitions in nanowires of a nonstoichiometric vanadium oxide bronze

机译：非化学计量的氧化钒青铜纳米线中的大规模金属-绝缘体跃迁的合成，光谱表征和观察

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Metal-insulator transitions in strongly correlated materials, induced by varying either temperature or dopant concentration, remain a topic of enduring interest in solid-state chemistry and physics owing to their fundamental importance in answering longstanding questions regarding correlation effects. We note here the unprecedented observation of a four-orders-of-magnitude metal-insulator transition in single nanowires of δ-K_xV _2O_5, when temperature is varied, which thus represents a rare new addition to the pantheon of materials exhibiting pronounced metal-insulator transitions in proximity to room temperature.

机译：由于温度或掺杂浓度的变化而引起的强相关材料中的金属-绝缘体转变，由于在回答有关关联效应的长期问题方面具有根本重要性，因此仍然是固态化学和物理领域中人们长期关注的话题。我们在这里注意到，当温度变化时，在δ-K_xV_2O_5的单根纳米线中，出现了四个数量级的金属-绝缘体跃迁的空前观察，这代表了显着的金属-绝缘体材料万神殿中罕见的新添加物在室温附近转变。

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《Nano letters》 |2010年第7期|共6页
作者
Patridge C.J.; Wu T.-L.; Jaye C.; Ravel B.; Takeuchi E.S.; Fischer D.A.; Sambandamurthy G.; Banerjee S.;
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正文语种 eng
中图分类特种结构材料;
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Metal-insulator transition; Nanowires; Solvothermal synthesis; Vanadium oxides; X-ray absorption spectroscopy;

机译：金属-绝缘体跃迁;纳米线;溶剂热合成;氧化钒;X射线吸收光谱;

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1. Synthesis, spectroscopic characterization, and observation of massive metal-insulator transitions in nanowires of a nonstoichiometric vanadium oxide bronze [J] . Patridge C.J., Wu T.-L., Jaye C., Nano letters . 2010,第7期

机译：非化学计量的氧化钒青铜纳米线中的大规模金属-绝缘体跃迁的合成，光谱表征和观察
2. Synthetic beta-K_(0.33)V_(2)O_(5) Nanorods: A Metal-Insulator Transition in Vanadium Oxide Bronze [J] . Xiaodong Zhang, Wensheng Yan, Yi Xie Chemistry, an Asian journal . 2011,第12期

机译：合成的β-K_（0.33）V_（2）O_（5）纳米棒：氧化钒青铜中的金属-绝缘体过渡
3. Single-step metal-insulator transition in thin film-based vanadium dioxide nanowires with a 20 nm electrode gap [J] . Tsuji Yoshihide, Kanki Teruo, Murakami Yasukazu, Applied physics express . 2019,第2期

机译：电极间隙为20 nm的基于薄膜的二氧化钒纳米线中的单步金属-绝缘体转变
4. Hydrothermal Synthesis, Spectroscopic, Optical and Electrochemical Characterization of Vanadium Dioxide Nanostructures [C] . Meenu, Bharti, Brijnandan S. Dehiya International Conference on Advances in Basic Sciences . 2019

机译：二氧化钒纳米结构的水热合成，光谱，光学和电化学表征
5. Electron spectroscopic study of 3d transition metal oxides and metal-insulator transitions. [D] . Park, Jaehoon. 1994

机译：3d过渡金属氧化物和金属-绝缘体过渡的电子光谱研究。
6. Correlating the Energetics and Atomic Motions of the Metal-Insulator Transition of M1 Vanadium Dioxide [O] . Jamie M. Booth, Daniel W. Drumm, Phil S. Casey, -1

机译：关联M1二氧化钒的金属-绝缘体跃迁的能量和原子运动
7. Synthesis of VO_2 Nanowire and Observation of the Metal-Insulator Transition [O] . Choi, Sungyoul, Kim, Bong-Jun, Lee, Yong-Wook, 2006

机译：VO_2纳米线的合成及金属绝缘子的观察过渡
8. Mesoscopic Effects and Metal-Insulator Transition in Vanadium Oxide Nanowires. [R] . Cobden, D. H. 2012

机译：钒氧化物纳米线的介观效应和金属绝缘体转变。

Synthesis, spectroscopic characterization, and observation of massive metal-insulator transitions in nanowires of a nonstoichiometric vanadium oxide bronze

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