Dissymmetric carbon nanotubes by bipolar electrochemistry

Warakulwit C; Nguyen T; Majimel J; Delville MH; Lapeyre V; Garrigue P; Ravaine V; Limtrakul J; Kuhn A

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Dissymmetric carbon nanotubes by bipolar electrochemistry

机译：双极电化学法制备不对称碳纳米管

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Short carbon nanotubes have been modified selectively on one end with metal using a bulk technique based on bipolar electrochemistry. A stabilized suspension of nanotubes is introduced in a capillary containing an aqueous metal salt solution, and a high electric field is applied to orientate and polarize the individual tubes. During their transport through the capillary under sufficient polarization (30 W), each nanotube is the site of water oxidation on one end and the site of metal ion reduction on the other end with the size of the formed metal cluster being proportional to the potential drop along the nanotube.

机译：短碳纳米管已经使用基于双极电化学的本体技术在一端用金属选择性修饰。将稳定的纳米管悬浮液引入包含金属盐水溶液的毛细管中，并施加高电场以定向和极化各个管。在足够的极化度（30 W）下通过毛细管传输过程中，每个纳米管的一端都是水氧化的位置，另一端是金属离子还原的位置，形成的金属簇的大小与电势降成比例沿着纳米管。

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来源
《Nano letters》 |2008年第2期|共5页
作者
Warakulwit C; Nguyen T; Majimel J; Delville MH; Lapeyre V; Garrigue P; Ravaine V; Limtrakul J; Kuhn A;
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正文语种 eng
中图分类特种结构材料;
关键词
NANO TEST TUBES; JANUS PARTICLES; NANOPARTICLES; DEPOSITION; SURFACES; SPHERES; ELECTRODEPOSITION; MONOLAYERS; ANISOTROPY; PALLADIUM;

机译：纳米试管;J颗粒;纳米颗粒;沉积;表面;球;电沉积;单分子膜;各向异性;钯;

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1. Dissymmetric carbon nanotubes by bipolar electrochemistry [J] . Warakulwit C, Nguyen T, Majimel J, Nano letters . 2008,第2期

机译：双极电化学法制备不对称碳纳米管
2. Electrochemistry at Carbon Nanotube Electrodes: Is the Nanotube Tip More Active Than the Sidewall? [J] . Kuanping Gong, Supriya Chakrabarti, Liming Dai Angewandte Chemie . 2008,第29期

机译：碳纳米管电极上的电化学：纳米管尖端比侧壁更活跃吗？
3. The effects of the lengths and orientations of single-walled carbon nanotubes on the electrochemistry of nanotube-modified electrodes [J] . Gooding JJ, Chou A, Liu JQ, Electrochemistry communications . 2007,第7期

机译：单壁碳纳米管的长度和取向对纳米管修饰电极电化学的影响
4. Dissymmetric Metal Deposition on Carbon Nanotubes [C] . C. Warakulwit, M.-H. Delville, V. Ravaine, Nanotechnology 2009 : Technical proceedings . 2009

机译：碳纳米管上的不对称金属沉积
5. The use of bipolar electrochemistry in nanoscience: Contact free methods for the site selective modification of nanostructured carbon materials. [D] . Ndungu, Patrick Gathura. 2004

机译：双极电化学在纳米科学中的应用：用于纳米结构碳材料的位点选择性修饰的无接触方法。
6. Direct Electrochemistry of Hemoglobin Immobilized on a Functionalized Multi-Walled Carbon Nanotubes and Gold Nanoparticles Nanocomplex-Modified Glassy Carbon Electrode [O] . Jun Hong, Ying-Xue Zhao, Bao-Lin Xiao, 2013

机译：血红蛋白的直接电化学固定在功能化的多壁碳纳米管和金纳米粒子纳米复合物修饰的玻碳电极上
7. Dissymmetric Carbon Nanotubes by Bipolar Electrochemistry [O] . -1

机译：双极电化学的不对称碳纳米管
8. Fabrication and Characterization of Multi-Walled Carbon Nanotube (MWCNT) and Ni-Coated Multi-Walled Carbon Nanotube (Ni-MWCNT) Repair Patches for Carbon Fiber Reinforced Composite Systems [R] . Johnson, B., Caraccio, A., Tate, L. N., 2011

机译：碳纤维增强复合材料多壁碳纳米管（mWCNT）和Ni涂层多壁碳纳米管（Ni-mWCNT）修补补片的制备与表征

Dissymmetric carbon nanotubes by bipolar electrochemistry

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