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Electrokinetic behaviour of overlapped electric double layers in nanofluidic channels

机译:纳米流体通道中重叠的双电层的电动行为

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摘要

The ionic concentration variation arising in overlapped electric double layers in nanochannels presents different electrokinetic behaviour from that in microchannels. Using a modified concentration approach, the results reveal that the surface charge density is insensitive to the concentration in the low-salt regime, and a nearly constant streaming conductance is predicted. A scaling analysis confirms that the streaming potential also has a constant value because of length scale effects, but not due to the accumulated charge in the double layer.
机译:纳米通道中重叠的双电层中产生的离子浓度变化呈现出与微通道中不同的电动行为。使用改进的浓度方法,结果表明,在低盐条件下,表面电荷密度对浓度不敏感,并且预测了几乎恒定的流电导。缩放分析证实,由于长度缩放效应,而不是由于双层中的累积电荷,流电势也具有恒定值。

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