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Direct integration of metal oxide nanowires into an effective gas sensing device

机译:将金属氧化物纳米线直接集成到有效的气体传感设备中

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摘要

A simple and large-area scalable methodology has been set up for direct integration of metal xide nanowire bundles into a functional device for gas sensing. It is based on sequential application of two consolidated techniques, namely high temperature vapour transport and condensation for fabrication of metal oxide nanowires, and wet etching of a sacrificial layer. The alumina substrate patterned with a silicon dioxide sacrificial layer does not influence the growth of nanowires and remains unaltered under the high temperature process. The sacrificial layer is finally removed under hydrofluoric acid, the metal oxide nanowires do not suffer modifications and a clean substrate surface can be obtained for deposition of stable metal contacts. The methodology was proven effective for application in a gas sensor device. Electrical measurements indicate that a slightly rectifying Schottky junction is present at low temperatures (up to T = 150 C) between nanowires and platinum electrodes, which vanishes as the temperature increases and under high voltage (bias voltage above 3 V). The results foresee the possibility of growth and integration of nanowire bundles directly into devices, overcoming the need for expensive and time-consuming nanomanipulation techniques.
机译:已经建立了一种简单且可大面积扩展的方法,用于将金属氧化物纳米线束直接集成到用于气体传感的功能设备中。它基于两种整合技术的顺序应用,即用于金属氧化物纳米线制造的高温蒸汽传输和冷凝,以及牺牲层的湿蚀刻。图案化有二氧化硅牺牲层的氧化铝基材不会影响纳米线的生长,并且在高温工艺下保持不变。最终在氢氟酸下去除牺牲层,金属氧化物纳米线不发生改性,并且可以获得干净的衬底表面以沉积稳定的金属触点。经验证,该方法可有效应用于气体传感器设备。电学测量表明,纳米线和铂电极之间在低温(最高​​T = 150 C)下存在轻微整流的肖特基结,随着温度的升高和高电压(3 V以上的偏置电压)消失。结果预见了将纳米线束直接生长和集成到设备中的可能性,从而克服了对昂贵且费时的纳米处理技术的需求。

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