Facile synthesis of zinc hydroxide carbonate flowers on zinc oxide nanorods with attractive luminescent and optochemical performance

Mao J.; Li J.-J.; Ling T.; Liu H.; Yang J.; Du X.-W.

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Facile synthesis of zinc hydroxide carbonate flowers on zinc oxide nanorods with attractive luminescent and optochemical performance

机译：在氧化锌纳米棒上轻松合成碳酸锌氢氧化物花，具有吸引人的发光和光化学性能

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A simple synthesis route was designed to fabricate a functional composite, zinc hydroxide carbonate (ZHC) flowers on zinc oxide (ZnO) nanorods. The hydrolysis of hexamethylenetetramine (HMT) can generate various species which are slowly released and gradually change reaction modes in a Zn(NO _3)_2/HMT solution. As a result, ZnO nanorods and ZHC flowers can be sequentially synthesized and connect very well under constant experimental conditions. The obtained composite has the advantages of both components and exhibits attractive properties. For instance, ZHC flowers on ZnO nanorods exhibit strong blue emission under the excitation of ultraviolet light, and dye-sensitized solar cells with the annealed composite as photoanode achieve much higher conversion efficiency than pure nanorod arrays.

机译：设计了一种简单的合成路线，以在氧化锌（ZnO）纳米棒上制备功能性复合材料碳酸氢氧化锌（ZHC）花。六亚甲基四胺（HMT）的水解可生成各种物质，这些物质在Zn（NO _3）_2 / HMT溶液中缓慢释放并逐渐改变反应模式。结果，可以连续合成ZnO纳米棒和ZHC花，并在恒定的实验条件下很好地连接。所获得的复合材料具有两种组分的优点并且表现出吸引人的性能。例如，ZnO纳米棒上的ZHC花在紫外光的激发下显示出强烈的蓝色发射，并且以退火复合材料作为光阳极的染料敏化太阳能电池比纯纳米棒阵列具有更高的转换效率。

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《Nanotechnology》 |2011年第24期|共7页
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Mao J.; Li J.-J.; Ling T.; Liu H.; Yang J.; Du X.-W.;
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1. Facile synthesis of zinc hydroxide carbonate flowers on zinc oxide nanorods with attractive luminescent and optochemical performance [J] . Mao J., Li J.-J., Ling T., Nanotechnology . 2011,第24期

机译：在氧化锌纳米棒上轻松合成碳酸锌氢氧化物花，具有吸引人的发光和光化学性能
2. Facile one-pot synthesis of nano-zinc hydroxide by electro-dissolution of zinc as a sacrificial anode and the application for adsorption of Th4+, U4+, and Ce4+ from aqueous solution [J] . Kamaraj Ramakrishnan, Vasudevan Subramanyan Research on Chemical Intermediates . 2016,第5期

机译：以锌为牺牲阳极电溶法一锅法合成纳米氢氧化锌及其在水溶液中吸附Th4 +，U4 +和Ce4 +的应用
3. Facile synthesis and the exploration of the zinc storage mechanism of beta-MnO2 nanorods with exposed (101) planes as a novel cathode material for high performance eco-friendly zinc-ion batteries [J] . Islam Saiful, Alfaruqi Muhammad Hilmy, Mathew Vinod, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2017,第44期

机译：容易合成及β-MnO2纳米棒锌贮藏机理的探测，暴露（101）平面为高性能环保锌离子电池的新型阴极材料
4. Synthesis of Zinc Carbonate Hydroxide Nanoparticles Using Microemulsion Process [C] . Tamer Alhawi, Mohammad Rehan, David York World Congress on Particle Technology . 2015

机译：使用微乳液法合成碳酸锌氢氧化物纳米粒子
5. The polarization and corrosion characterization of zinc and modified zinc in concentrated alkali metal hydroxide electrolyte: The effect of a zinc oxide/hydroxide surface. [D] . Catino, John W., Jr. 1989

机译：浓碱金属氢氧化物电解质中锌和改性锌的极化和腐蚀特征：氧化锌/氢氧化物表面的影响。
6. Facile Synthesis of ZnO Nanorods by Microwave Irradiation of Zinc–Hydrazine Hydrate Complex [O] . DenthajeKrishna Bhat 2008

机译：微波辐射锌水合肼配合物轻松合成ZnO纳米棒
7. Facile synthesis of oriented zinc oxide seed layer for the hydrothermal growth of zinc oxide nanorods [O] . SFU Farhad, NI Tanvir, MS Bashar, 2018

机译：氧化锌纳米杆水热生长的取向氧化锌种子层的容易合成

Facile synthesis of zinc hydroxide carbonate flowers on zinc oxide nanorods with attractive luminescent and optochemical performance

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