Palladium nanowires stabilized by thiol-functionalized ionic liquid: seed-mediated synthesis and heterogeneous catalyst for Sonogashira coupling reaction

Gao SY; Zhang HJ; Wang XM; Mai WP; Peng CY; Ge LH

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Palladium nanowires stabilized by thiol-functionalized ionic liquid: seed-mediated synthesis and heterogeneous catalyst for Sonogashira coupling reaction

机译：巯基官能化离子液体稳定的钯纳米线：种子介导的合成和Sonogashira偶联反应的非均相催化剂

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With the recent surge of the use of room-temperature ionic liquids in the syntheses of inorganic nanomaterials, we have successfully integrated the advantages of a thiol-functionalized ionic liquid and the seed growth method to generate palladium nanowires at room temperature. Moreover, the as-prepared palladium nanowires show very high catalytic activity and stability for the Sonogashira coupling reaction.

机译：随着最近在无机纳米材料的合成中使用室温离子液体的热潮，我们成功地整合了硫醇官能化离子液体的优点和种子生长方法，以在室温下生成钯纳米线。此外，所制备的钯纳米线显示出非常高的催化活性和对Sonogashira偶联反应的稳定性。

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《Nanotechnology》 |2005年第8期|共4页
作者
Gao SY; Zhang HJ; Wang XM; Mai WP; Peng CY; Ge LH;
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正文语种 eng
中图分类一般工业技术;
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ONE-STEP SYNTHESIS; PD NANOPARTICLES; HYDROGENATION REACTIONS; GOLD NANOPARTICLES; CARBON NANOTUBES; ARYL; SIZE; DEPOSITION; HECK; ALKYNYLSILANES;

机译：一步合成;PD纳米颗粒;加氢反应;金纳米颗粒;碳纳米管;芳烃;尺寸;沉积;颈;烷基LSI;

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1. Palladium nanowires stabilized by thiol-functionalized ionic liquid: seed-mediated synthesis and heterogeneous catalyst for Sonogashira coupling reaction [J] . Gao SY, Zhang HJ, Wang XM, Nanotechnology . 2005,第8期

机译：巯基官能化离子液体稳定的钯纳米线：种子介导的合成和Sonogashira偶联反应的非均相催化剂
2. Carbon dioxide pressure induced heterogeneous and homogeneous Heck and Sonogashira coupling reactions using fluorinated palladium complex catalysts [J] . Y. Akiyama, X. Meng, S. Fujita The Journal of Supercritical Fluids . 2009,第2期

机译：使用氟化钯配合物催化剂，二氧化碳压力引起的非均相和均相Heck和Sonogashira偶联反应
3. Bis(pyrimidine)-based palladium catalysts: synthesis, X-ray structure and applications in Heck-, Suzuki-, Sonogashira-Hagihara couplings and amination reactions [J] . Michael R. Buchmeiser, Thomas Schareina, Rhett Kempe, Journal of Organometallic Chemistry . 2001,第1期

机译：双（嘧啶）基钯催化剂：合成，X射线结构及其在Heck-，Suzuki-，Sonogashira-Hagihara偶联和胺化反应中的应用
4. Electrospun Heterogeneous Palladium Catalyst for Sonogashira Coupling Reaction [C] . Liping Chen, Yonghong Li, Xiaoyan Li PMSE Symposia . 2009

机译：Sonogashira偶联反应的Electromun异质钯催化剂
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Palladium-catalyzed Sonogashira coupling reactions in γ-valerolactone-based ionic liquids [O] . László Orha, József M Tukacs, László Kollár, 2019

机译：γ-戊内酯基离子液体中钯催化的Sonogashira偶联反应
7. Carbon dioxide pressure induced heterogeneous and homogeneous Heck and Sonogashira coupling reactions using fluorinated palladium complex catalysts [O] . Akiyama, Y., Meng, X., Fujita, S., 2009

机译：使用氟化钯配合物催化剂，二氧化碳压力引起的非均相和均相Heck和Sonogashira偶联反应

Palladium nanowires stabilized by thiol-functionalized ionic liquid: seed-mediated synthesis and heterogeneous catalyst for Sonogashira coupling reaction

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