(2-Ethyl-5-oxo-hexyl)Methylthiomethyl Phthalate as By-product of the Swern Oxidation:Improved Synthesis of Ring-deuterated Major Metabolites of Bis(2-ethylhexyl)Phthalate

Hans-Detlev Gilsing; Jurgen Angerer; Dietrich Prescher

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(2-Ethyl-5-oxo-hexyl)Methylthiomethyl Phthalate as By-product of the Swern Oxidation:Improved Synthesis of Ring-deuterated Major Metabolites of Bis(2-ethylhexyl)Phthalate

机译：氧化的副产物（2-乙基-5-氧杂己基）甲硫基甲基邻苯二甲酸酯：双（2-乙基己基）邻苯二甲酸酯的环氘代主要代谢物的合成改进

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Two ring-deuterated major metabolites of bis(2-ethylhexyl)phthalate were obtained in excellent yields by means of an improved oxidation procedure.The by-product of their interconversion by Swern oxidation is elucidated and a possible mechanism of its formation is proposed.

机译：通过改进的氧化工艺，以优异的收率获得了两个环氘化的邻苯二甲酸二（2-乙基己基）酯的主要代谢物，阐明了它们通过Swern氧化相互转化的副产物，并提出了其形成的可能机理。

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来源
《Monatshefte fur Chemie》 |2003年第9期|共7页
作者
Hans-Detlev Gilsing; Jurgen Angerer; Dietrich Prescher;
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正文语种 eng
中图分类化学;
关键词
bis(2-ethylhexyl)phthalate; metabolites; isotopic labeling; oxidations; methylthiomethyl esters;

机译：邻苯二甲酸二（2-乙基己基）酯;代谢物;同位素标记;氧化;甲硫基甲基酯;

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1. (2-Ethyl-5-oxo-hexyl)Methylthiomethyl Phthalate as By-product of the Swern Oxidation:Improved Synthesis of Ring-deuterated Major Metabolites of Bis(2-ethylhexyl)Phthalate [J] . Hans-Detlev Gilsing, Jurgen Angerer, Dietrich Prescher Monatshefte fur Chemie . 2003,第9期

机译：氧化的副产物（2-乙基-5-氧杂己基）甲硫基甲基邻苯二甲酸酯：双（2-乙基己基）邻苯二甲酸酯的环氘代主要代谢物的合成改进
2. Kinetics of di(2-ethylhexyl) phthalate (DEHP) and mono(2-ethylhexyl) phthalate in blood and of DEHP metabolites in urine of male volunteers after single ingestion of ring-deuterated DEHP [J] . KesslerW., NumtipW., V?lkelW., Toxicology and Applied Pharmacology . 2012,第2期

机译：单次摄入环氘DEHP的男性志愿者血液中邻苯二甲酸二（2-乙基己基）酯（DEHP）和邻苯二甲酸单（2-乙基己基）酯的动力学以及尿液中DEHP代谢物的动力学
3. Unified reversed-phase method for the determination of Di(2-ethylhexyl) phthalate and its major metabolite, mono (2-ethylhexyl) phthalate, in biological samples [J] . Sircar D, Albazi SJ, Atallah Y, Journal of liquid chromatography and related technologies . 2006,第17a20期

机译：统一反相方法测定生物样品中邻苯二甲酸二（2-乙基己基）邻苯二甲酸酯及其主要代谢物邻苯二甲酸单（2-乙基己基）酯
4. Development and Validation of a UPLC-MS/MS Method for Mono(2-ethylhexyl)phthalate, a Metabolite of Di(2-ethylhexyl)phthalate, in Rat Plasma, Amniotic Fluid, and Fetus [C] . Melanie Silinski, Brenda Fletcher, Reshan Fernando, ASMS Conference on Mass Spectrometry and Allied Topics . 2016

机译：对Mono（2-乙基己基）邻苯二甲酸酯，DI（2-乙基己基）邻苯二甲酸代谢物，大鼠等离子体，羊水和胎儿的邻苯二甲酸酯的开发和验证
5. Quantitative assessment of bis(2-ethylhexyl) phthalate in Commonly-consumed foods and elucidation of its natural component in stilton cheese by compound specific carbon isotope analysis . [D] . Nelson, Michael Andrew. 2013

机译：通过复合比碳同位素分析定量评估普通食用食品中邻苯二甲酸二（2-乙基己基）邻苯二甲酸酯的含量，并确定斯蒂尔顿干酪中邻苯二甲酸双（2-乙基己基）酯的天然成分。
6. The in vitro serum protein-binding characteristics of bis-(2-ethylhexyl) phthalate and its principal metabolite mono-(2-ethylhexyl) phthalate. [O] . W C Griffiths, P D Camara, A Saritelli, 1988

机译：邻苯二甲酸双-（2-乙基己基）及其主要代谢产物邻苯二甲酸单-（2-乙基己基）的体外血清蛋白结合特性。
7. The in vitro serum protein-binding characteristics of bis-(2-ethylhexyl) phthalate and its principal metabolite, mono-(2-ethylhexyl) phthalate. [O] . Griffiths, W C, Camara, P D, Saritelli, A, 1988

机译：邻苯二甲酸双-（2-乙基己基）及其主要代谢产物邻苯二甲酸单-（2-乙基己基）的体外血清蛋白结合特性。
8. Canadian Environmental Protection Act Priority Substances List Assessment Report:Bis(2-ethylhexyl) Phthalate [R] . 1994

机译：加拿大环境保护法优先物质清单评估报告：邻苯二甲酸二（2-乙基己基）酯

(2-Ethyl-5-oxo-hexyl)Methylthiomethyl Phthalate as By-product of the Swern Oxidation:Improved Synthesis of Ring-deuterated Major Metabolites of Bis(2-ethylhexyl)Phthalate

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