Crystal engineering of brominated tectons:N-methyl-3,5-dibromo-pyridinium iodide gives particularly short C-Br...I halogen bonding

Thomas A.Logothetis; Franck Meyer; Pierangelo Metrangolo; Tullio Pilati; Giuseppe Resnati

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Crystal engineering of brominated tectons:N-methyl-3,5-dibromo-pyridinium iodide gives particularly short C-Br...I halogen bonding

机译：溴化构造的晶体工程：N-甲基-3,5-二溴碘化碘鎓使C-Br ... I卤素键特别短

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The crystal matrix of N-methyl-3,5-dibromopyridinium iodide is constituted of infinite helices where the cation and the anion alternate and are bound by the second shortest reported C-Br...I halogen bonding.The electron poor pyridinium scaffold is particularly effective in boosting the electron acceptor ability of bromine substituents.

机译：N-甲基-3,5-二溴吡啶鎓碘化物的晶体基质由无限螺旋组成，其中阳离子和阴离子交替并由第二短的报道的C-Br ... I卤素键结合。在增强溴取代基的电子受体能力方面特别有效。

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《New Journal of Chemistry》 |2004年第6期|共4页
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Thomas A.Logothetis; Franck Meyer; Pierangelo Metrangolo; Tullio Pilati; Giuseppe Resnati;
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中图分类化学;
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1. Crystal engineering of brominated tectons:N-methyl-3,5-dibromo-pyridinium iodide gives particularly short C-Br...I halogen bonding [J] . Thomas A.Logothetis, Franck Meyer, Pierangelo Metrangolo, New Journal of Chemistry . 2004,第6期

机译：溴化构造的晶体工程：N-甲基-3,5-二溴碘化碘鎓使C-Br ... I卤素键特别短
2. Exploring Supramolecular Self-Assembly of Tetraarylporphyrins by Halogen Bonding: Crystal Engineering with Diversely Functionalized Six-Coordinate Tin(L)_2-Porphyrin Tectons [J] . Hatem M. Titi, Ranjan Patra, Israel Goldberg Chemistry: A European journal . 2013,第44期

机译：通过卤素键研究四芳基卟啉的超分子自组装：具有多种功能的六坐标锡（L）_2-卟啉构造子的晶体工程。
3. Dendrimeric tectons in halogen bonding-based crystal engineering [J] . Metrangolo P, Meyer F, Pilati T, Crystal growth & design . 2008,第2期

机译：基于卤素键的晶体工程中的树枝状结构
4. Haloperfluorocarbons: Versatile Tectons in Halogen Bonding Based Crystal Engineering [C] . Pierangelo Metrangolo, Franck Meyer, Giuseppe Resnati, American Chemical Society Symposium on Fluorine-Containing Synthons . 2005

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5. Crystal Engineering with Coordination, Hydrogen- and Halogen-Bonds, and the Construction of Porous Solids [D] . Gunawardana, Chamara Abeywickramasinghe 2018

机译：配位键，氢键和卤素键的晶体工程以及多孔固体的构建
6. Studies of Halogen Bonding Induced by Pentafluorosulfanyl Aryl Iodides: A Potential Group of Halogen Bond Donors in a Rational Drug Design [O] . Yuji Sumii, Kenta Sasaki, Seiji Tsuzuki, 2019

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7. Competing hydrogen-bond and halogen-bond donors in crystal engineering [O] . Aakeröy Christer B., Panikkattu Sheelu, Chopade Prashant D., 2013

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8. Solid State Synthesis Under Supramolecular Control of a 2D Heterotetratopic Self-complementary Tecton Tailored to Halogen Bonding [R] . Marras, G. , Metrangolo, P. , Meyer, F. , 2006

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Crystal engineering of brominated tectons:N-methyl-3,5-dibromo-pyridinium iodide gives particularly short C-Br...I halogen bonding

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