Catalytic aziridinations with copper(II) salen complexes

Wei Sun; Eberhardt Herdtweck; Fritz E.Kuhn

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Catalytic aziridinations with copper(II) salen complexes

机译：赛伦铜（II）络合物的催化叠氮化

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Three copper(II) complexes coordinated with salen ligands are synthesized,characterized,and examined for catalytic nitrene transfer reactions with a set of olefins.All three copper(II) complexes exhibit catalytic reactivity for the aziridination of styrene with PhI=NTs.Complex 3 is the most efficient catalyst for activated olefins (up to 94% yield).This complex is additionally characterized by X-ray crystallography,showing a highly distorted octahedral ligand surrounding the Cu atom having included in its coordination sphere an acetate ligand.

机译：合成，表征和表征了三种与Salen配体配合的铜（II）配合物与一组烯烃的催化腈转移反应。所有三种铜（II）配合物均对PhI = NTs的苯乙烯氮杂叠氮化反应具有催化活性。是络合物的最有效催化剂（产率高达94％）。该配合物还通过X射线晶体学表征，表明在铜原子周围高度扭曲的八面体配体在其配位球体中包含乙酸酯配体。

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《New Journal of Chemistry》 |2005年第12期|共4页
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Wei Sun; Eberhardt Herdtweck; Fritz E.Kuhn;
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1. Catalytic aziridinations with copper(II) salen complexes [J] . Wei Sun, Eberhardt Herdtweck, Fritz E.Kuhn New Journal of Chemistry . 2005,第12期

机译：赛伦铜（II）络合物的催化叠氮化
2. Tethering of Cu(II), Co(II) and Fe(III) tetrahydro-salen and salen complexes onto amino-functionalized SBA-15: Effects of salen ligand hydrogenation on catalytic performances for aerobic epoxidation of styrene [J] . Ying Yang, Ying Zhang, Shijie Hao Chemical engineering journal . 2011,第3期

机译：将Cu（II），Co（II）和Fe（III）四氢salen和salen配合物束缚到氨基官能化的SBA-15上：Salen配体加氢对苯乙烯的好氧环氧化催化性能的影响
3. Copper(ii) complexes incorporating poly/perfluorinated alkoxyaluminate-type weakly coordinating anions: Syntheses, characterization and catalytic application in stereoselective olefin aziridination [J] . Li Y., He J., Khankhoje V., Dalton transactions: An international journal of inorganic chemistry . 2011,第21期

机译：含聚/全氟烷氧基铝酸盐型弱配位阴离子的铜（ii）配合物：在立体选择性烯烃叠氮化中的合成，表征和催化应用
4. Zeolite-encapsulated Co( II), Mn( II), Cu( II) and Cr(III) salen complexes as catalysts for efficient selective oxidation of benzyl alcohol [C] . F H Li, H Bi, D XHuang International Conference on New Material and Chemical Industry . 2018

机译：沸石 - 包封的CO（II），Mn（II），Cu（II）和Cr（III）盐配合物作为催化剂，用于有效选择性氧化苄醇
5. Catalytic olefin cyclopropanation and oxidation using (salen)iron(III) complexes. [D] . Edulji, Smita K. 2004

机译：催化烯烃环丙烷化和氧化使用（salen）铁（III）配合物。
6. Oligomeric (Salen)Mn(III) Complexes Featuring Tartrate Linkers Immobilized over Layered Double Hydroxide for Catalytically Asymmetric Epoxidation of Unfunctionalized Olefins [O] . Yihong Jia, Asma A. ALOthman, Rui Liang, 2020

机译：寡聚（Salen）Mn（III）配合物其具有固定在层状双氢氧化物上的酒石酸酯的连接剂用于催化不官能化烯烃的不对称环氧化
7. Axially dissymmetric binaphthyldiimine chiral salen-type ligands for copper-catalyzed asymmetric aziridination [O] . Shi M, Wang CJ, Chan ASC 2001

机译：铜不对称叠氮基团的轴向不对称联萘二胺手性萨伦型配体
8. Studies of the Complexes Formed Between the 5-Trifluoromethyletetrazol Anion and Some Divalent Transition Metal Ions. Magnetochemical and Spectral Studies of Some Copper (II) Complexes of Substituted Benzoic Acids. Copper (II) Halide Complexes with Substituted Pyridine n-Oxides [R] . Harris, A. D., Jonassen, H. B., Mallory, T. L., 1964

机译：5-三氟甲基四唑阴离子与一些二价过渡金属离子形成的配合物的研究。一些取代苯甲酸铜（Ⅱ）配合物的磁化学和光谱研究。具有取代的吡啶n-氧化物的铜（II）卤化物配合物

Catalytic aziridinations with copper(II) salen complexes

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