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Hemicyanine-DNA-complex: Application to solid-state dye lasers

机译:半菁-DNA复合物:应用于固态染料激光器

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摘要

Many cationic cyanine dyes show strong fluorescence enhancement when they interact with DNA double strand. In this paper, we studied a hemicyanine dye, 4-[4-(dimethylamino)stylyl] -1-dococylpyridnium bromide (DMASDPB), which is a typical nonlinear optical compound but has not been attracted as a light emitter because of its low fluorescence efficiency. We fabricated DNA-CTMA-DMASDPB complex thin films by spin coating from chloroform/ethanol solution, and demonstrated laser emissions from the films. Their wavelength tuning (600-630 nm) was achieved by changing the angle between two pumping beams interfering on the samples. We also made a durability test under continuous excitation of 3 mJ/ cm2 with 10 Hz about an hour, showing that the degradation of the emission was about 20%.
机译:当许多阳离子花青染料与DNA双链相互作用时,它们会显示出强大的荧光增强作用。在本文中,我们研究了半花青染料4- [4-(二甲基氨基)苯乙烯基] -1-二十二烷基溴化吡啶(DMASDPB),这是一种典型的非线性光学化合物,但由于其荧光低而未被吸引。效率。我们通过从氯仿/乙醇溶液中旋涂制备了DNA-CTMA-DMASDPB复合薄膜,并证明了薄膜的激光发射。通过改变干涉样品的两个泵浦光束之间的角度,可以实现其波长调谐(600-630 nm)。我们还在3 mJ / cm2和10 Hz的连续激发下进行了大约一个小时的耐久性测试,表明发射的衰减约为20%。

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