C–H bond activation and S-atom transfer from cobalt(III) thiolate and isothiocyanate complexes

Hongwei Xu; Paul G. Williard; Wesley H. Bernskoetter

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C–H bond activation and S-atom transfer from cobalt(III) thiolate and isothiocyanate complexes

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The cobalt phenylthiolate complex, cis,mer-(PMe_3)_3Co(CH_3)_2SPh, was found to undergo competitive two-electron ethane reductive elimination and C–H bond cyclometallation. The thiophenolato bound cobaltacycle was generated via C–H bond oxidative addition to a five-coordinate intermediate followed by rapid methane elimination. A related cobalt isothiocyanate complex, cis,mer-(PMe_3)_3Co(CH_3)_2NCS, was also prepared and found to perform ethane elimination and S-atom transfer to yield trimethylphosphine sulfide. This rare example of S-atom donation from a isothiocyanate was characterized by NMR and GC-MS analysis, with cis,mer-(PMe_3)_3Co(CH_3)_2CN identified as one of the cobalt based products.

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2014年第39期|14696-14700|共5页
作者
Hongwei Xu; Paul G. Williard; Wesley H. Bernskoetter;
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作者单位

Department of Chemistry, Brown University, Providence, RI 02912, USA.;

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原文格式 PDF
正文语种英语
中图分类化学;无机化学;
关键词
bond; activation; transfer;

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1. Metal-mediated reaction modeled on nature: the activation of isothiocyanates initiated by zinc thiolate complexes [J] . Eger W.A., Presselt M., Jahn B.O.Schmitt M.Popp J.Anders E. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第8期

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2. THE LIGAND CAGE EFFECT IN VOLUMES OF ACTIVATION FOR ELECTRON TRANSFER REACTIONS OF COBALT(III/II) COMPLEXES IN AQUEOUS SOLUTION [J] . Shalders RD., Swaddle TW. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第19期

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C–H bond activation and S-atom transfer from cobalt(III) thiolate and isothiocyanate complexes

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