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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Lattice distortion and orbital hybridization in NdFeO3-PbTiO3 ferroelectric thin films
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Lattice distortion and orbital hybridization in NdFeO3-PbTiO3 ferroelectric thin films

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Single-phase xNdFeO(3)-(1 - x) PbTiO3 thin films with different dopant contents were fabricated on the Pt(111)/Ti/SiO2/Si substrate by a sol-gel route. Grain size was influenced by the dopant content effectively. A synchrotron radiation X-ray diffraction study revealed a reduced tetragonality (c/a) of the PbTiO3 lattice in the films. Distortion of the TiO6 octahedron was weakened, as investigated by Raman scattering and X- ray absorption spectra. An electronic structural study indicated that the hybridizations between O 2p and Pb 6s and Ti 3d orbitals were weakened. The decrease of lattice distortion and orbital hybridization gives rise to degradation of the ferroelectric nature in the films.

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