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Catalytic deeolorization of methyl orange by the rectorite-sulflte system

机译:累托石-硫酸盐体系催化甲基橙脱氯

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The simple rectorite-sulfite system has been found to decolorize methyl orange efficiently with dioxygen as the oxidant under mild conditions. The rectorite was also stable during the reaction without significant metal ions leaching. The iron impurity, mainly presented as highly dispersed hematite, probably acted as the active centers. Suggested by the electron spin resonance spin-trapping technologies and radical scavenger measurements, the produced sulfate radicals were to be responsible for the dye deeolorization. This study can provide us a simple, effective and economic system ideal for the treatment of toxic and nonbiodegradable azo dye.
机译:已发现简单的累托石-亚硫酸盐体系可在温和的条件下用双氧作为氧化剂有效地使甲基橙脱色。累托石在反应期间也是稳定的,没有明显的金属离子浸出。主要表现为高度分散的赤铁矿的铁杂质可能充当了活性中心。通过电子自旋共振自旋俘获技术和自由基清除剂的测量表明,产生的硫酸根自由基是造成染料脱氯的原因。这项研究可以为我们提供一种简单,有效且经济的系统,用于处理有毒且不可生物降解的偶氮染料。

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