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首页> 外文期刊>Rapid Communications in Mass Spectrometry: RCM >Magic bimetallic cluster anions of M/Pb (M = Au, Ag and Cu) observed and analyzed by laser ablation and time-of-flight mass spectrometry
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Magic bimetallic cluster anions of M/Pb (M = Au, Ag and Cu) observed and analyzed by laser ablation and time-of-flight mass spectrometry

机译:通过激光烧蚀和飞行时间质谱法观察和分析了M / Pb(M = Au,Ag和Cu)的魔术双金属簇阴离子

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摘要

By using laser ablation on mixtures of coinage metals M (Cu, Ag, Au) and lead, M/Pb binary cluster anions containing up to tens of atoms were produced and analyzed. Most of the magic clusters discovered can be described based on the electron shell models which were deduced from simple homogeneous metal cluster systems. The clustering activities of coinage metals and lead were also compared with the properties of their bulk binary alloys. Copyright (C) 2003 John Wiley Sons, Ltd. [References: 22]
机译:通过在造币金属M(Cu,Ag,Au)和铅的混合物上进行激光烧蚀,生产和分析了M / Pb二元簇阴离子,其阴离子含量高达数十个。可以根据从简单的均质金属团簇系统推导的电子壳模型来描述发现的大多数魔术团簇。还比较了造币金属和铅的聚集活性及其块状二元合金的性能。版权所有(C)2003 John Wiley Sons,Ltd. [引用:22]

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