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Novel polysulphonates and poly(sulphonate-co-carbonate)polymers for nuclear track detection

机译:用于核径迹检测的新型聚磺酸盐和聚(磺酸盐-共碳酸)聚合物

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摘要

Preparation of homopolymer from diethylene glycol bis(allyl sulphonate)(DEAS)and its several copolymers with allyl diglycol carbonate(ADC)and their preliminary evaluation as nuclear track detector is described.The monomer is synthesized by reacting diethylene glycol with allyl sulphonyl chloride in presence of pyridine as a base.Spectral characteristics of the monomer are also given for the first time.The designed polymers were successfully tested for detection of ~(239)Pu alpha particles and ~(252)Cf fission fragment tracks after etching with 6 N NaOH at 70 °C.Some of the polymers prepared showed even better sensitivity than(SR-86)(20)track detectors for track detection properties.The polymers are also compared with commercial CR-39 track detectors for its track detection properties.
机译:描述了由二甘醇双(烯丙基磺酸盐)(DEAS)制备均聚物及其与碳酸烯丙二二醇酯(ADC)的几种共聚物及其在核径迹检测器中的初步评价。该单体是通过使二甘醇与烯丙基磺酰氯在存在下反应合成的首次给出了单体的光谱特征。设计的聚合物已成功测试以6 N NaOH腐蚀后〜(239)Puα粒子和〜(252)Cf裂变碎片径迹的检测。在70°C的条件下,所制备的某些聚合物显示出比(SR-86)(20)轨道检测器更高的灵敏度,并且可以与商用CR-39轨道检测器进行比较。

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