Three Zn(II)/Cd(II/Mn(II) coordination polymers based on a 2-hydroxy-N-(1H-tetrazol-5-yl) benzamide ligand: structures, and magnetic and photoluminescence propertiest

Zou Yang; Chen Jing; Li Yuan-Yuan; Li Li; Liu Jian-Lan; Ren Xiao-Ming

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Three Zn(II)/Cd(II/Mn(II) coordination polymers based on a 2-hydroxy-N-(1H-tetrazol-5-yl) benzamide ligand: structures, and magnetic and photoluminescence propertiest

机译：基于2-羟基-N-（1H-四唑-5-基）苯甲酰胺配体的三种Zn（II）/ Cd（II / Mn（II）配位聚合物：结构，磁性和光致发光性质

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Three coordination polymers, {[Zn(L)(2)] center dot H2O)(n) (1), {[Cd(L)(2)]center dot H2O}(n) (2) and {[Mn(L)2]center dot H2O), (3) (HL = 2hydroxy-N-1H-tetrazol-5-ylbenzamide), have been prepared under hydrothermal conditions. X-ray diffraction analysis reveals that compounds 1-3 are isomorphous, showing an interdigitated 3-D framework with 1-D channels. Fluorescence studies show that the emissions of complexes 1-2 are attributed to the ligand pi-pi* transition. Magnetic studies indicate that compound 3 exhibits antiferromagnetic properties.

机译：三种配位聚合物，{[Zn（L）（2）]中心点H2O）（n）（1），{[Cd（L）（2）]中心点H2O}（n）（2）和{[Mn（ L）2]中心点H 2 O），（3）（HL ＝ 2-羟基-N-1H-四唑-5-基苯甲酰胺），是在水热条件下制备的。 X射线衍射分析表明化合物1-3是同构的，显示了具有1-D通道的叉指式3-D骨架。荧光研究表明，配合物1-2的发射归因于配体pi-pi *跃迁。磁性研究表明化合物3具有反铁磁性。

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《RSC Advances》 |2015年第96期|共6页
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Zou Yang; Chen Jing; Li Yuan-Yuan; Li Li; Liu Jian-Lan; Ren Xiao-Ming;
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Three Zn(II)/Cd(II/Mn(II) coordination polymers based on a 2-hydroxy-N-(1H-tetrazol-5-yl) benzamide ligand: structures, and magnetic and photoluminescence propertiest

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