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Efficiency enhancement of organic solar cells using peroxo-polytitanic acid coated silver nanowires as transparent electrodes

机译:使用过氧-聚钛酸涂层的银纳米线作为透明电极提高有机太阳能电池的效率

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Solution-processed transparent electrodes made from silver-nanowires and peroxo-polytitanic (PPT) acid gel were developed for enhancing efficiency of organic solar cells. The electronic and optical properties of multilayer silver nanowires were significantly improved through the interconnection layers of amorphous titanium oxide (TiOx) from PPT acid gel. The AgNW-TiOx composite film showed averaged 92.14% optical transmittance with only 16.01 Omega sq(-1) sheet resistance. Combining the transparent electrodes with poly(3-hexylthiophene):[ 6,6]-phenyl-C61-butyric acid methyl ester (P3HT: PC61BM) blend, the efficiency of organic solar cells was 1.45 times that of devices using an ITO electrode. Optical simulations verified that the improvement was attributed to the enhanced near-field absorption and substantial scattering of incident light resulted from the random nature of the AgNW-TiOx core-shell nanostructure.
机译:为了提高有机太阳能电池的效率,开发了由银纳米线和过氧聚钛酸(PPT)酸性凝胶制成的溶液处理透明电极。通过来自PPT酸性凝胶的无定形氧化钛(TiOx)的互连层,多层银纳米线的电子和光学性能得到了显着改善。 AgNW-TiOx复合膜的平均光学透射率为92.14%,而薄层电阻仅为16.01 Omega sq(-1)。将透明电极与聚(3-己基噻吩):[6,6]-苯基-C61-丁酸甲酯(P3HT:PC61BM)混合物结合使用,有机太阳能电池的效率是使用ITO电极的器件的1.45倍。光学模拟证明,这种改进归因于AgNW-TiOx核-壳纳米结构的随机性,增强了近场吸收和入射光的大量散射。

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