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An amino-decorated NbO-type metal-organic framework for high C2H2 storage and selective CO2 capture

机译:氨基装饰的NbO型金属有机框架,可实现高C2H2储存和选择性CO2捕集

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摘要

A novel amino-decorated NbO-type metal-organic framework [Cu-2(C22H11NO8)(H2O)(2)]center dot(DMF)(6)center dot(H2O), (ZJU-8, ZJU = Zhejiang University; DMF = N,N-dimethylformamide) has been synthesized and structurally characterized. The activated ZJU-8a exhibits both a high C2H2 uptake capacity (195 cm(3) g(-1) at 1 bar) and a moderately high adsorption selectivity for CO2 over N-2 (12.27) and CH4 (7.38) at room temperature.
机译:一种新型的氨基修饰的NbO型金属有机骨架[Cu-2(C22H11NO8)(H2O)(2)]中心点(DMF)(6)中心点(H2O),(ZJU-8,ZJU =浙江大学;已合成DMF = N,N-二甲基甲酰胺)并对其结构进行了表征。活化的ZJU-8a在室温下既显示出高的C2H2吸收能力(195 bar下为195 cm(3)g(-1)),还具有在N-2(12.27)和CH4(7.38)上对CO2的中等选择性吸附。

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