A novel Pd/C-catalyzed conversion of glucose to 1,2-propanediol by water splitting with Zn

Wang Jie; Yao Guodong; Wang Yuanqing; Zhang Hua; Huo Zhibao; Jin Fangming

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A novel Pd/C-catalyzed conversion of glucose to 1,2-propanediol by water splitting with Zn

机译：锌水分解法新的钯/碳催化葡萄糖转化为1,2-丙二醇

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A novel Pd/C-catalysed conversion of glucose to 1,2-propanediol by water splitting with Zn was proposed. The yield of 1,2-akanediols reached 48%, mainly including 1,2-propanediol (33.3%), the reported highest yield from glucose. Water, as a solvent, provides an in situ and active hydrogen source. The formed ZnO acts as a catalyst with Pd/C.

机译：提出了一种新的钯/碳催化的锌水分解葡萄糖转化为1,2-丙二醇的方法。 1,2-链烷二醇的收率达到48％，主要包括1,2-丙二醇（33.3％），据报道是葡萄糖的最高收率。水作为溶剂，可提供原位和活性氢源。形成的ZnO用作Pd / C的催化剂。

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《RSC Advances》 |2015年第63期|共5页
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Wang Jie; Yao Guodong; Wang Yuanqing; Zhang Hua; Huo Zhibao; Jin Fangming;
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1. A novel Pd/C-catalyzed conversion of glucose to 1,2-propanediol by water splitting with Zn [J] . Wang Jie, Yao Guodong, Wang Yuanqing, RSC Advances . 2015,第63期

机译：锌水分解法新的钯/碳催化葡萄糖转化为1,2-丙二醇
2. Pd/C-catalyzed heterocyclization during copper-free Sonogashira coupling: synthesis of 2-benzylimidazo[1,2-a]pyrimidines in water [J] . Mohammad Bakherad, Ali Keivanloo, Zahra Kalantar Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2011,第2期

机译：无铜Sonogashira偶联过程中Pd / C催化的杂环化：水中2-苄基咪唑并[1,2-a]嘧啶的合成
3. Efficient and selective conversion of glycidol to 1,2-propanediol over Pd/C catalyst [J] . Cucciniello Raffaele, Pironti Concetta, Capacchione Carmine, Catalysis Communications . 2016,第Null期

机译：在Pd / C催化剂上高效缩水缩水甘油转化为1,2-丙二醇
4. Optical Resolution of Racemic 3-Chloro-1,2-propanediol with a Mushroom,Pleurotus Eryngii, to give (+)-3-Chloro-1,2-propanediol and with another Mushroom, Agaricus Bisporus, to give (-)-3-Chioro-1,2-propanediol [C] . Xian-Hua HE, Si-Qian WANG, Mei-Yu HUANG, 5th International Symposium on High-Tech Polymer Materials（HTPM-V）（第五届国际高技术高分子材料学术会议）论文集 . 2008

机译：外消旋3-氯1,2-丙二醇与蘑菇白灵菇的光学拆分，得到（+）-3-氯1,2-丙二醇与另一种蘑菇双孢蘑菇，得到（-）-3 -Chioro-1,2-丙二醇
5. PduL is an evolutionary distinct phosphotransacylase involved in B12-dependent 1,2-propanediol degradation by Salmonella enterica serovar Typhimurium LT2 and is associated with the propanediol utilization microcompartments [D] . Liu, Yu 2009

机译：PduL是一种进化独特的磷酸转酰酶，参与肠炎沙门氏菌血清鼠伤寒沙门氏菌LT2降解B12依赖的1,2-丙二醇，并与丙二醇利用微区室相关
6. Pd/C-catalyzed copper-free Sonogashira coupling: one-pot synthesis of 1-aryl-4-(2-phenylethynyl)124triazolo43-aquinoxalines in water [O] . Mohammad Bakherad, Saeideh Jajarmi -1

机译：Pd / C催化的无铜Sonogashira偶联：在水中一锅合成1-芳基-4-（2-苯基乙炔基）124三唑并43-a喹喔啉
7. Computer augumented modelling studies of Pb(II), Cd(II), Hg(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes of L-glutamic acid in 1,2-propanediol–water mixtures [O] . MAHESWARA RAO VEGI, PADMA LATHA MUDDAPU, SIVA RAO TIRUKKUVALLURI, 2008

机译：L-谷氨酸在1,2-中的pb（II），Cd（II），Hg（II），Co（II），Ni（II），Cu（II）和Zn（II）配合物的计算机增强模拟研究丙二醇 - 水混合物

A novel Pd/C-catalyzed conversion of glucose to 1,2-propanediol by water splitting with Zn

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