Direct C-H amination and C-H chloroamination of 7-deazapurines

Sabat Nazarii; Klecka Martin; Slavetinska Lenka; Klepetarova Blanka; Hocek Michal

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Direct C-H amination and C-H chloroamination of 7-deazapurines

机译：7-脱氮嘌呤的直接C-H胺化和C-H氯胺化

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Protocols for selective Pd-Cu-catalyzed direct C-H amination or C-H chloroamination of 7-deazapurines with N-chloro-N-alkyl-arylsulfonamides have been developed leading either to 8-(arylsulfonyl)methylamino-7-deazapurines or to 7-chloro-8-(arylsulfonyl)methylamino-7-deazapurines. The scope and limitations of the methods, as well as synthesis of a small series of 6,8,9-tri- and 6,7,8,9-tetrasubstituted 7-deazapurines and deprotection of the sulfonamide are presented.

机译：已经开发了用N-氯-N-烷基-芳基磺酰胺选择性地进行Pd-Cu催化的7-脱氮嘌呤直接CH胺化或CH氯胺化的方案，导致8-（芳基磺酰基）甲基氨基-7-脱氮嘌呤或7-氯-氮杂嘌呤。 8-（芳基磺酰基）甲基氨基-7-脱氮嘌呤。介绍了该方法的范围和局限性，以及小系列的6,8,9-三-和6,7,8,9-四取代的7-脱氮嘌呤的合成和磺酰胺的脱保护。

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《RSC Advances》 |2014年第107期|共4页
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Sabat Nazarii; Klecka Martin; Slavetinska Lenka; Klepetarova Blanka; Hocek Michal;
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1. Direct C-H amination and C-H chloroamination of 7-deazapurines [J] . Sabat Nazarii, Klecka Martin, Slavetinska Lenka, RSC Advances . 2014,第107期

机译：7-脱氮嘌呤的直接C-H胺化和C-H氯胺化
2. Fused Pyrrolo[2,3-d]pyrimidines (7-Deazapurines) by Palladium-Catalyzed Direct N-H and C-H Arylation Reactions [J] . Dodonova Jelena, Tumkevicius Sigitas Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2017,第11期

机译：用钯催化直接N-H和C-H芳基化反应融合吡咯并[2,3-D]嘧啶（7-二氮杂藻）
3. Synthesis of 8-(1,2,3-triazol-1-y1)-7-deazapurine nucleosides by azide-alkyne click reactions and direct C-H bond functionalization [J] . Kavoosi Sam, Rayala Ramanjaneyulu, Walsh Brenna, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2016,第39期

机译：通过叠氮化物-炔烃点击反应和直接的C-H键官能化合成8-（1,2,3-三唑-1-y1）-7-脱氮嘌呤核苷
4. Capturing All the Major Fleeting Intermediates of a Catalytic Cycle Using Desorption Electrospray Ionization: C-H Amination [C] . Richard H. Perry, Thomas J. Cahill III, Jennifer L. Roizen, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2012

机译：使用解吸电喷雾电离捕获催化循环的所有主要短暂中间体：C-H胺化
5. Copper-catalyzed functionalization of alkenes: Carboamination, C-H amination, C-H alkylation and carboetherifcation reactions. [D] . Liwosz, Timothy Walter. 2014

机译：铜催化烯烃的官能化：碳氨基化，C-H氨基化，C-H烷基化和碳醚化反应。
6. Synthesis of 8-(123-triazol-1-yl)-7-deazapurine nucleosides by azide-alkyne click reactions and direct C-H bond functionalization [O] . Sam Kavoosi, Ramanjaneyulu Rayala, Brenna Walsh, -1

机译：叠氮化物-炔烃点击反应和直接的C-H键官能化反应合成8-（123-三唑-1-基）-7-脱氮嘌呤核苷
7. Direct C–H amination and C–H chloroamination of 7-deazapurines [O] . Nazarii Sabat, Martin Klečka, Lenka Slavětínská, 2014

机译：直接C-H胺化和7-二氮杂藻的C-H氯化
8. Direct Selective Acylation of an Unactivated C-H Bond in a Caged Hydrocarbon.Approach to Systems for C-H Bond Functionalization That Proceed Catalytically and Selectively at High Substrate Conversion [R] . Prosser-McCartha, C. M., Hill, C. L. 1990

机译：笼型烃中未活化C-H键的直接选择性酰化。用于C-H键官能化的系统，在高基质转化下催化和选择性地进行

Direct C-H amination and C-H chloroamination of 7-deazapurines

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