Bottom-up approach to engineer a molybdenum-doped covalent-organic framework catalyst for selective oxidation reaction

Zhang Weijie; Jiang Pingping; Wang Ying; Zhang Jian; Gao Yongxue; Zhang Pingbo

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Bottom-up approach to engineer a molybdenum-doped covalent-organic framework catalyst for selective oxidation reaction

机译：自下而上的方法来设计钼掺杂的共价有机骨架催化剂以进行选择性氧化反应

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摘要

We synthesized a readily accessible molybdenum-doped covalent-organic framework catalyst (Mo-COF) linked by a hydrazine linkage via a facile two-step bottom-up approach. This Mo-COF catalyst, as an open nanochannel-reactor, exhibited promising catalytic activity for the selective oxidation reaction.

机译：我们合成了一种容易获得的钼掺杂的共价有机骨架催化剂（Mo-COF），该肼催化剂通过便捷的两步自下而上方法通过肼键连接。这种Mo-COF催化剂作为开放式纳米通道反应器，对选择性氧化反应显示出有希望的催化活性。

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《RSC Advances》 |2014年第93期|共4页
作者
Zhang Weijie; Jiang Pingping; Wang Ying; Zhang Jian; Gao Yongxue; Zhang Pingbo;
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1. Bottom-up approach to engineer a molybdenum-doped covalent-organic framework catalyst for selective oxidation reaction [J] . Zhang Weijie, Jiang Pingping, Wang Ying, RSC Advances . 2014,第93期

机译：自下而上的方法来设计钼掺杂的共价有机骨架催化剂以进行选择性氧化反应
2. Post-synthetic Modification of DUT-5-based Metal Organic Frameworks for the Generation of Single-site Catalysts and their Application in Selective Epoxidation Reactions [J] . Yildiz Ceylan, Kutonova Ksenia, Osswald Simon, ChemCatChem . 2020,第4期

机译：基于DUT-5的金属有机框架的合成后修饰用于产生单次催化剂的产生及其在选择性环氧化反应中的应用
3. A novel approach to understanding and modelling performance evolution of catalysts during their initial operation under reaction conditions-Case study of vanadium phosphorus oxides for n-butane selective oxidation [J] . Wilkinson S.K., Simmons M.J.H., Stitt E.H., Journal of Catalysis . 2013,第Null期

机译：一种了解和模拟催化剂在反应条件下初始运行过程中性能演变的新方法-以正丁烷选择性氧化钒磷氧化物为例
4. ENGINEERED MYOGLOBIN CATALYSTS FOR SELECTIVE CARBENE TRANSFER REACTIONS [C] . Rudi Fasan Conference on biochemical and molecular engineering . 2019

机译：用于选择性碳转移反应的工程化的肌红蛋白催化剂
5. A fundamental study of selective oxidation reactions on supported vanadium oxide catalysts: Reaction mechanism and structure-activity relationships. [D] . Feng, Tao. 2004

机译：负载型钒氧化物催化剂上选择性氧化反应的基础研究：反应机理和结构-活性关系。
6. Porphyrin-Based Metal-Organic Frameworks as Heterogeneous Catalysts in Oxidation Reactions [O] . Carla F. Pereira, Mário M. Q. Simões, João P. C. Tomé, 2016

机译：卟啉基金属有机骨架在氧化反应中作为多相催化剂
7. Bifunctional Noble-Metal-Free Catalyst for the Selective Aerobic Oxidation-Knoevenagel One-Pot Reaction: Encapsulation of Polyoxometalates into an Alkylamine-Modified MIL-101 Framework [O] . -1

机译：用于选择性有氧氧化的双功能贵金属 - 无金属催化剂，单锅反应：将多氧化胍酸盐包封到烷基胺改性的MIL-101框架中
8. NMR Studies of Catalysts: Phosphorous-31 and Vanadium-51 in Vanadium-Phosphorous-Oxygen Selective Oxidation Catalysts and the Selective Averaging of the Second Order Quadrupolar Interaction in Aluminosilicates [R] . Walker, R. D. 1987

机译：催化剂的核磁共振研究：钒 - 磷 - 氧选择氧化催化剂中的磷-31和钒-51以及硅铝酸盐中二阶四极相互作用的选择性平均

Bottom-up approach to engineer a molybdenum-doped covalent-organic framework catalyst for selective oxidation reaction

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