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Synthesis of PVC/CNT nanocomposite fibers using a simple deposition technique for the application of Alizarin Red S (ARS) removal

机译:使用简单沉积技术合成PVC / CNT纳米复合纤维以应用茜素红S(ARS)去除

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摘要

This paper reports the synthesis of PVC/CNT nanocomposite fibers using a simple deposition technique as well as their application towards removal of Alizarin Red S (ARS). The as-prepared PVC/CNT nanocomposite fibers were characterized by Brunauer, Emmett and Teller surface area measurements, Raman spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, transmission electron microscopy, scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry and diffuse reflectance spectroscopy. PVC/CNT nanocomposite fibers showed a remarkable 81% increase in surface area compared to the PVC fibers. PVC/CNT nanocomposite fibers showed a lower band gap and higher glass transition temperature than the PVC fibers. Both PVC and PVC/CNT nanocomposite fibers were applied to adsorb ARS and the nanocomposite fibers showed almost double the adsorption capacity than PVC fibers. The thermodynamic study revealed that adsorption of ARS was exothermic in nature and physical forces were involved in adsorption of dye onto PVC and PVC/CNT nanocomposite fibers.
机译:本文报道了使用简单的沉积技术合成PVC / CNT纳米复合纤维及其在去除茜素红S(ARS)中的应用。通过Brunauer,Emmett和Teller表面积测量,拉曼光谱,X射线光电子能谱,X射线衍射,透射电子显微镜,扫描电子显微镜,热重分析,差示扫描量热和漫反射光谱法。与PVC纤维相比,PVC / CNT纳米复合纤维的表面积显着增加了81%。 PVC / CNT纳米复合纤维比PVC纤维具有更低的带隙和更高的玻璃化转变温度。 PVC和PVC / CNT纳米复合纤维均用于吸附ARS,纳米复合纤维的吸附能力几乎是PVC纤维的两倍。热力学研究表明,ARS的吸附性质是放热的,物理力与染料在PVC和PVC / CNT / CNT纳米复合纤维上的吸附有关。

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