Mild and highly efficient metal-free oxidative alpha-cyanation of N-acyl/sulfonyl tetrahydroisoquinolines

Yan Changcun; Liu Yuxiu; Wang Qingmin

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Mild and highly efficient metal-free oxidative alpha-cyanation of N-acyl/sulfonyl tetrahydroisoquinolines

机译：N-酰基/磺酰基四氢异喹啉的轻度高效无金属氧化性氰化

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A highly efficient metal-free oxidative alpha-cyanation reaction of N-acyl/sulfonyl tetrahydroisoquinolines under mild conditions was developed. The reaction uses 2,2,6,6-tetramethylpiperidine N-oxide fluoroborate salt (T+BF4-) as the oxidant and trimethylsilyl cyanide as the source of the cyano group.

机译：在温和条件下，开发了N-酰基/磺酰基四氢异喹啉的高效无金属氧化α-氰化反应。该反应使用2,2,6,6-四甲基哌啶N-氧化物氟硼酸盐（T + BF4-）作为氧化剂，并使用三甲基甲硅烷基氰化物作为氰基的来源。

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《RSC Advances》 |2014年第104期|共4页
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Yan Changcun; Liu Yuxiu; Wang Qingmin;
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正文语种 eng
中图分类化学;
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1. Mild and highly efficient metal-free oxidative alpha-cyanation of N-acyl/sulfonyl tetrahydroisoquinolines [J] . Yan Changcun, Liu Yuxiu, Wang Qingmin RSC Advances . 2014,第104期

机译：N-酰基/磺酰基四氢异喹啉的轻度高效无金属氧化性氰化
2. A Review on Metal-Free Oxidative alpha-Cyanation and Alkynylation of N-Substituted Tetrahydroisoquinolines as a Rapid Route for the Synthesis of Isoquinoline Alkaloids [J] . Kouznetsov Vladimir V., Ortiz-Villamizar Marlyn C., Mendez-Vargas Leonor Y., Current organic chemistry . 2020,第8期

机译：N-取代的四羟基喹啉的无金属氧化α-氰基氰化物及醇烷基化综述作为异喹啉生物碱合成的快速途径
3. Highly efficient fixation of carbon dioxide to cyclic carbonates with new multi-hydroxyl bis-(quaternary ammonium) ionic liquids as metal-free catalysts under mild conditions [J] . Peng Jing, Wang Sheng, Yang Hai-Jian, Fuel . 2018,第Jul15期

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4. (Invited) Boron and Nitrogen Co-Doped Porous Carbon Nanofibers As Metal-Free Electrocatalysts for Highly Efficient Ammonia Electrosynthesis [C] . Yang Hou, Yan Kong Meeting of the Electrochemical Society;International Meeting on Chemical Sensors . 2020

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6. DDQ-Promoted Mild and Efficient Metal-Free Oxidative α-Cyanation of N-Acyl/Sulfonyl 1234-Tetrahydroisoquinolines [O] . Hong Pyo Kim, Heesun Yu, Hyoungsu Kim, 2018

机译：DDQ促进N-酰基/磺酰基1234-四氢异喹啉的轻度和高效无金属氧化α-氰化
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机译：通过2,3-二氯-5,6-二氰基-1,4-苯醌（DDQ）氧化，通过2,3-二氯-5,6-二氰基 - 1,4-苯并醌（DDQ）氧化，直接和高效的C（SP3）-H官能化（Thiqs）用电子富含核酸的亲核试剂
8. Metal-free and Oxygen-free Graphene as Oxygen Reduction Catalysts for Highly Efficient Fuel Cells. [R] . J. Baek L. Dai 2013

机译：无金属和无氧石墨烯作为高效燃料电池的氧还原催化剂。

Mild and highly efficient metal-free oxidative alpha-cyanation of N-acyl/sulfonyl tetrahydroisoquinolines

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