Silver-catalyzed decarboxylative acylation of arylglyoxylic acids with arylboronic acids

Cheng Kai; Zhao Baoli; Qi Chenze

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Silver-catalyzed decarboxylative acylation of arylglyoxylic acids with arylboronic acids

机译：芳基乙醛酸与芳基硼酸的银催化脱羧酰化

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The silver-catalyzed coupling of arylboronic acids with arylglyoxylic acids was found to be an extremely efficient route for the synthesis of unsymmetrical diaryl ketones. It can be conducted on a gram scale under mild and open-flask conditions with good functional group compatibility, avoiding the addition of expensive and/or toxic metals.

机译：发现芳基硼酸与芳基乙醛酸的银催化偶联是合成不对称二芳基酮的极其有效的途径。它可以在温和开瓶条件下以克规模进行，并具有良好的官能团相容性，避免添加昂贵和/或有毒金属。

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《RSC Advances》 |2014年第89期|共5页
作者
Cheng Kai; Zhao Baoli; Qi Chenze;
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正文语种 eng
中图分类化学;
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1. Silver-catalyzed decarboxylative acylation of arylglyoxylic acids with arylboronic acids [J] . Cheng Kai, Zhao Baoli, Qi Chenze RSC Advances . 2014,第89期

机译：芳基乙醛酸与芳基硼酸的银催化脱羧酰化
2. Silver-catalyzed decarboxylative acylation of quinoxalin-2(1: H)-ones with α-oxo-carboxylic acids [J] . Zeng Xiaobao, Liu Chulong, Wang Xingyong, Organic & biomolecular chemistry . 2017,第42期

机译：银催化的喹喔啉-2（1：H）-ones与α-氧代羧酸的脱羧酰化反应
3. Palladium catalyzed decarboxylative acylation of arylboronic acid with ethyl cyanoacetate as a new acylating agent: synthesis of alkyl aryl ketones [J] . Yousuf Md, Das Tuluma, Adhikari Susanta New Journal of Chemistry . 2015,第11期

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4. Organocatalytic Decarboxylative Functionalization of Carboxylic Acids [C] . Kazumasa Kitahara, Misaki Katada, Seiji Iwasa 日本化学会春季年会講演予稿集 . 2018

机译：有机催化脱羧羧酸脱羧官能化
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6. Chemoselective O-acylation of hydroxyamino acids and amino alcohols under acidic reaction conditions: History scope and applications [O] . Tor E Kristensen 2015

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7. Palladium-Catalyzed Decarboxylative Ortho-Acylation of Tertiary Benzamides with Arylglyoxylic Acids [O] . Joydev K. Laha, Ketul V. Patel, Sheetal Sharma 2017

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Silver-catalyzed decarboxylative acylation of arylglyoxylic acids with arylboronic acids

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