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Synthetic application of gold nanoparticles and auric chloride for the synthesis of 5-substituted 1H-tetrazoles

机译:金纳米颗粒和氯化金在5取代1H-四唑合成中的合成应用

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摘要

An effective one-pot, convenient gold catalyzed synthesis of 5-substituted 1H-tetrazoles has been discussed. The study demonstrated the comparative overview for utilization of gold(III) and gold nanoparticles (spheres) as a catalyst. Detailed understandings of the mechanism, surface area effect (in reference to nanoparticles) of gold in the activation of nitriles for nucleophilic (3+2) cycloaddition of sodium azide to give the product have also been studied.
机译:已经讨论了有效的一锅,方便的金催化的5-取代的1H-四唑的合成。该研究证明了金(III)和金纳米颗粒(球)用作催化剂的比较概述。还研究了机理的详细理解,研究了金在腈活化叠氮化钠的亲核性(3 + 2)环化生成产品中的表面积效应(相对于纳米粒子)。

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