Reactions of beta-diketone compounds with nitriles catalyzed by Lewis acids: a simple approach to beta-enaminone synthesis

Cheng Xu; Pei Shuchen; Xue Chenchen; Cao Kaifei; Hai Li; Wu Yong

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Reactions of beta-diketone compounds with nitriles catalyzed by Lewis acids: a simple approach to beta-enaminone synthesis

机译：β-二酮化合物与路易斯酸催化的腈的反应：β-烯胺酮合成的简单方法

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摘要

Aluminium chloride selectively promoted the nucleophilic attack of beta-diketone compounds with nitriles to give enaminones. Moreover a plausible mechanism for this transformation was given.

机译：氯化铝选择性地促进β-二酮化合物与腈的亲核攻击，从而生成烯胺酮。此外，给出了这种转化的合理机制。

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《RSC Advances》 |2014年第109期|共4页
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Cheng Xu; Pei Shuchen; Xue Chenchen; Cao Kaifei; Hai Li; Wu Yong;
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正文语种 eng
中图分类化学;
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1. Reactions of beta-diketone compounds with nitriles catalyzed by Lewis acids: a simple approach to beta-enaminone synthesis [J] . Cheng Xu, Pei Shuchen, Xue Chenchen, RSC Advances . 2014,第109期

机译：β-二酮化合物与路易斯酸催化的腈的反应：β-烯胺酮合成的简单方法
2. Diastereoselective synthesis of tetrahydrofurans by Lewis acid catalyzed intermolecular carbenoid-carbonyl reaction-cycloaddition sequences: Unusual diastereoselectivity of Lewis acid catalyzed cycloadditions [J] . Hashimoto Y., Itoh K., Kakehi A., The Journal of Organic Chemistry . 2013,第12期

机译：刘易斯酸催化的分子间类胡萝卜素-羰基反应-环加成序列的非对映选择性合成：刘易斯酸催化的环加成反应的非对映选择性
3. Synthesis of nitrile coordinated Lewis acids Al(OC(CF3)2R)3 and their application in catalytic epoxide ring-opening reactions [J] . Yang Li, Yi Tan, Eberhardt Herdtweck Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2010,第1a2期

机译：腈配位路易斯酸Al（OC（CF3）2R）3的合成及其在催化环氧化物开环反应中的应用
4. Synthesis and Characterization of Pheox- and Phebox-Al Complexes and Its Application to the Lewis Acid Catalyzed Reactions [C] . Shuichi Nakao, Yoshihiro Nishimoto, Makoto Yasuda 日本化学会春季年会講演予稿集 . 2018

机译：嗜磷酸和浮藻硅络合物的合成与表征及其在路易斯酸催化反应中的应用
5. THE MECHANISM OF LEWIS ACID CATALYZED ENE REACTIONS. LEWIS ACID CATALYZED INTER- AND INTRAMOLECULAR (2+2) CYCLOADDITIONS OF CONJUGATED ALLENIC ESTERS TO ALKENES. THE REGIOCHEMISTRY OF TRIETHYLAMINE DEPROTONATION OF ALPHA, BETA-UNSATURATED ACID CHLORIDES TO FORM VINYLKETENES. ATTEMPTED SYNTHESIS OF ALPHA-BOURBONENE. [D] . RON, EYAL. 1987

机译：路易斯酸催化的烯反应的机理。路易斯酸将共轭的烯丙基酯间和分子内（2 + 2）的循环负载成烯烃。乙酰胺，β-不饱和酸氯化物形成乙烯基酮的三乙胺质子化反应的区域化学。尝试合成Alpha-Bourbonene。
6. Direct Synthesis of 5-Aryl Barbituric Acids by Rhodium(II)-Catalyzed Reactions of Arenes with Diazo Compounds [O] . Daniel Best, David J Burns, Hon Wai Lam -1

机译：铑（II）催化芳烃与重氮化合物的反应直接合成5-芳基巴比妥酸
7. The Acid Catalyzed Decomposition of Diazo Compounds. I. Synthesis of Oxazoles in the BF3Catalyzed Reaction of Diazo Carbonyl Compounds with Nitriles [O] . Toshikazu Ibata, Ryohei Sato 1979

机译：酸催化重氮化合物的分解。 I.用腈的二氮杂羰基化合物的BF3CATalyzed反应合成恶唑
8. Electrophilic Displacement Reactions Involving Organoboron Compounds Some Preliminary Observations on the Acid Catalyzed Hydrolysis of Arene-boronic Acids [R] . K. V. Nahabedian, H. G. Kuivlila 1956

机译：涉及有机硼化合物的亲电位移反应对酸催化芳烃 - 硼酸水解的初步观察

Reactions of beta-diketone compounds with nitriles catalyzed by Lewis acids: a simple approach to beta-enaminone synthesis

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