Metal-free, visible-light photoredox catalysis: transformation of arylmethyl bromides to alcohols and aldehydes

Li Jian; Wang Hongni; Liu Li; Sun Jiangtao

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Metal-free, visible-light photoredox catalysis: transformation of arylmethyl bromides to alcohols and aldehydes

机译：无金属，可见光的光氧化还原催化：芳基甲基溴化物转化为醇和醛

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A mild, simple, and controllable metal-free photocatalytic system for the transformation of arylmethyl bromides to corresponding alcohols and aldehydes in high yields with visible-light irradiation has been achieved. Eosin Y was found to be an efficient promoter for this oxidative dehalogenation reaction under photo irradiation conditions.

机译：已经实现了一种温和，简单且可控制的无金属光催化体系，该体系可通过可见光辐射将芳基甲基溴化物高产率地转化为相应的醇和醛。发现曙红Y是光照射条件下该氧化脱卤反应的有效促进剂。

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《RSC Advances》 |2014年第91期|共5页
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Li Jian; Wang Hongni; Liu Li; Sun Jiangtao;
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正文语种 eng
中图分类化学;
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1. Metal-free, visible-light photoredox catalysis: transformation of arylmethyl bromides to alcohols and aldehydes [J] . Li Jian, Wang Hongni, Liu Li, RSC Advances . 2014,第91期

机译：无金属，可见光的光氧化还原催化：芳基甲基溴化物转化为醇和醛
2. Visible-Light Photoredox-Catalyzed Thioacetalization of Aldehydes Under Metal-Free and Solvent-Free Conditions [J] . Du Kai, Wang Shao-Chien, Basha R. Sidick, Advanced synthesis & catalysis . 2019,第7期

机译：无金属和无溶剂条件下的可见光光致氧催化醛的硫代乙醛
3. Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis [J] . Qiang Fu, Zhi-Yu Bo, Jian-Heng Ye, Nature Communications . 2019,第1期

机译：通过可见光光致催化与二氧化碳的烯烃的无金属膦酰基化与二氧化碳的无金属膦酸酯
4. C(sp3 )-H Cyanation Promoted by Visible-Light Photoredox/Phosphate Hybrid Catalysis [C] . Takayuki Wakaki, Kentaro Sakai 日本化学会春季年会講演予稿集 . 2018

机译：C（SP3）-H用可见光光毒剂/磷酸杂交催化促进的氰化
5. Synthetic applications of visible-light photoredox catalysis. [D] . Tucker, Joseph Walter. 2013

机译：可见光光氧化还原催化的合成应用。
6. Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis [O] . Qiang Fu, Zhi-Yu Bo, Jian-Heng Ye, -1

机译：可见光光氧化还原催化用二氧化碳实现烯烃的无过渡金属膦酰基羧化
7. Enantioselective 1,2-Addition of Aminoalkyl Radical to Aldehydes via Visible-Light Photoredox Initiated Chiral Oxazaborolidinium Ion Catalysis [O] . -1

机译：通过可见光的光毒剂引发的手性恶唑啉烷离子催化，对醛基氨基烷基加入醛基氨基烷基的氨基烷基

Metal-free, visible-light photoredox catalysis: transformation of arylmethyl bromides to alcohols and aldehydes

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