Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates

Dai Xiaojun; Mao Renjie; Guan Baochuan; Xu Xiaoliang; Li Xiaonian

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Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates

机译：可见光光氧化还原催化：将氨基烷基自由基区域选择性地加成到2,3-烯丙基酯上

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The regioselective addition of alpha-aminoalkyl radicals to 2,3-allenoates by visible-light-mediated electron transfer using 1 mol% of Ru(bpy)(3)(BF4)(2) as a photocatalyst was successfully established. This photoredox protocol is a simple and effective method for the synthesis of unsaturated g-aminobutyric ester derivatives.

机译：成功建立了通过使用1 mol％的Ru（bpy）（3）（BF4）（2）作为光催化剂的可见光介导的电子转移，将α-氨基烷基自由基区域选择性加成到2,3-烯丙基酯上。该光氧化还原方案是一种合成不饱和g-氨基丁酸酯衍生物的简单有效的方法。

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《RSC Advances》 |2015年第68期|共5页
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Dai Xiaojun; Mao Renjie; Guan Baochuan; Xu Xiaoliang; Li Xiaonian;
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中图分类化学;
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1. Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates [J] . Dai Xiaojun, Mao Renjie, Guan Baochuan, RSC Advances . 2015,第68期

机译：可见光光氧化还原催化：将氨基烷基自由基区域选择性地加成到2,3-烯丙基酯上
2. Enantioselective 1,2-Addition of alpha-Aminoalkyl Radical to Aldehydes via Visible-Light Photoredox Initiated Chiral Oxazaborolidinium Ion Catalysis [J] . Kim Jae Yeon, Lee Yea Suel, Choi Yuna, ACS catalysis . 2020,第18期

机译：通过可见光光毒剂引发的手性恶唑唑烷烃离子催化，向醛进行映选择性1,2-加入醛基氨基烷基的α-氨基烷基
3. Heterogeneous Visible-Light Photoredox Catalysis with Graphitic Carbon Nitride for alpha-Aminoalkyl Radical Additions, Allylations, and Heteroarylations [J] . Cai Yunfei, Tang Yurong, Fan Lulu, ACS catalysis . 2018,第10期

机译：非均相可见光光毒剂与石墨碳氮化物用于α-氨基烷基的基团加成，烯丙基和杂芳基
4. Divergence in Photoredox Reaction:Radical Addition of α-BromoNitroalkanes to Styrene Derivatives [C] . Yuto Tsuchiya, RyotaOnai, Daisuke Uraguchi 日本化学会春季年会 . 2020

机译：光致毒剂反应中的分歧：将α-溴的根部加入苯乙烯衍生物
5. Visible light photocatalysis in the chemistry of radical ions and triplet nitrenes. [D] . Farney, Elliot Patrick. 2015

机译：可见光在自由基离子和三线态氮烯化学反应中的光催化作用。
6. Generation of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins [O] . Yuriy Slutskyy, Larry E. Overman -1

机译：可见光氧化还原催化生成甲氧羰基自由基及其与缺电子烯烃的共轭加成反应
7. Heterogeneous Visible-Light Photoredox Catalysis with Graphitic Carbon Nitride for Aminoalkyl Radical Additions Allylations, and Heteroarylations [O] . -1

机译：非均相可见光光毒剂催化与石墨氮化氨基烷基自由基添加烯丙基，以及杂芳基

Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates

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