Iodine-catalysed sp(3) C-H sulfonylation to form beta-dicarbonyl sulfones with sodium sulfinates

Gao Wen-Chao; Zhao Jin-Jin; Chang Hong-Hong; Li Xing; Liu Qiang; Wei Wen-Long

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Iodine-catalysed sp(3) C-H sulfonylation to form beta-dicarbonyl sulfones with sodium sulfinates

机译：碘催化的sp（3）C-H磺酰化与亚磺酸钠形成β-二羰基砜

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摘要

An efficient and easily handled method for beta-dicarbonyl sulfones with sodium sulfinates as the sulfonyl source was developed. This transformation was involved in the iodine-catalysed sp(3) C-H sulfonylation of beta-dicarbonyl compounds.

机译：开发了一种高效且易于处理的方法，以亚磺酸钠作为磺酰基源的β-二羰基砜。该转化参与了碘催化的β-二羰基化合物的sp（3）C-H磺酰化反应。

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《RSC Advances》 |2014年第90期|共4页
作者
Gao Wen-Chao; Zhao Jin-Jin; Chang Hong-Hong; Li Xing; Liu Qiang; Wei Wen-Long;
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正文语种 eng
中图分类化学;
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1. Iodine-catalysed sp(3) C-H sulfonylation to form beta-dicarbonyl sulfones with sodium sulfinates [J] . Gao Wen-Chao, Zhao Jin-Jin, Chang Hong-Hong, RSC Advances . 2014,第90期

机译：碘催化的sp（3）C-H磺酰化与亚磺酸钠形成β-二羰基砜
2. Direct Synthesis of Substituted (Z)-Allylic Sulfones by Palladium-Catalyzed Sulfonylation of Vinylethylene Carbonates with Sodium Sulfinates [J] . Ke Miaolin, Huang Guanxin, Ding Li, ChemCatChem . 2019,第19期

机译：用硫酸钠催化乙烯基碳酸亚乙烯酯的钯催化磺化硫化物直接合成取代的（Z）-allylic砜
3. Efficient sulfonylation of ketones with sodium sulfinates for the synthesis of β-keto sulfones [J] . Siqi Deng, En Liang, Yinrong Wu, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2018,第44期

机译：酮硫酸钠的高效磺酰化，用于合成β-酮砜的合成
4. Electrochemical Sulfonylation of Electron-Rich Aromatic Substrates with Sodium Sulfinates [C] . Joachim Nikl, Sebastian Lips, Siegfried R. Waldvogel Meeting of the Electrochemical Society;International Meeting on Chemical Sensors . 2020

机译：用硫酸钠的富含电子芳族底物的电化学硫化物
5. Radical sp3 C-H Functionalization of Amines and Alcohols [D] . Wappes, Ethan Albert. 2019

机译：胺和醇的自由基sp3 C-H功能化
6. Ligand-Mediated and Copper-Catalyzed C(sp3)-H Bond Functionalization of Aryl Ketones with Sodium Sulfinates under Mild Conditions [O] . Xing-Wang Lan, Nai-Xing Wang, Cui-Bing Bai, -1

机译：轻度条件下配体介导和铜催化的芳基酮与亚磺酸钠的C（sp3）-H键官能化
7. Cs2CO3-Mediated Regio- and Stereoselective Sulfonylation of 1,1-Dibromo-1-alkenes with Sodium Sulfinates [O] . Morteza Shiri, Parvin Salehi, Zeinab Mohammadpour, 2020

机译：CS2CO3介导的1,1-二溴-1-烯烃的介导的Regio和立体选择性硫化物，含硫酸钠

Iodine-catalysed sp(3) C-H sulfonylation to form beta-dicarbonyl sulfones with sodium sulfinates

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