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Enhanced extrinsic absorption promotes the visible light photocatalytic activity of wide band-gap (BiO)(2)CO3 hierarchical structure

机译:增强的外在吸收促进宽带隙(BiO)(2)CO3分层结构的可见光光催化活性

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摘要

(BiO)(2)CO3 hierarchical microspheres and (BiO)(2)CO3 nanoparticles with wide band-gaps were fabricated by a simple hydrothermal method. The former showed higher visible light photocatalytic activity towards the removal of NO than the latter due to the enhanced extrinsic absorption benefiting from the strong light reflecting and scattering effects. The extrinsic absorption over (BiO)(2)CO3 hierarchical microspheres can induce the production of holes and electrons with visible light, subsequently generating active species to participate in photocatalytic reactions.
机译:通过简单的水热法制备了具有宽禁带宽度的(BiO)(2)CO3分层微球和(BiO)(2)CO3纳米颗粒。前者对NO的去除表现出比后者更高的可见光光催化活性,这归因于外来吸收的增强,这得益于强的光反射和散射作用。在(BiO)(2)CO3分层微球上的外部吸收可诱导可见光产生空穴和电子,随后产生活性物质以参与光催化反应。

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