WCl6/DMF as a new reagent system for the phosphine-free Pd(0)-catalyzed aminocarbonylation of aryl halides

Iranpoor Nasser; Firouzabadi Habib; Rizi Zeinab Tavangar; Erfan Soodabeh

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WCl6/DMF as a new reagent system for the phosphine-free Pd(0)-catalyzed aminocarbonylation of aryl halides

机译：WCl6 / DMF作为无膦Pd（0）催化的芳基卤化物氨基羰基化的新试剂系统

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WCl6 in dimethyl formamide (DMF) is introduced as a new reagent system for aminocarbonylation of aryl halides in the presence of PdCl2 as pre-catalyst without any phosphorous ligand. Aryl iodides, bromides as well as chlorides were efficiently converted to their corresponding N, N-dimethyl amides in good to high yields. In this protocol, WCl6/DMF is responsible for the generation of both Pd(0) catalyst as well as the formation of a Vilsmeier imminium type intermediate.

机译：引入二甲基甲酰胺（DMF）中的WCl6作为一种新的试剂系统，用于在没有任何磷配体的PdCl2作为预催化剂存在下芳基卤化物的氨基羰基化。芳基碘化物，溴化物和氯化物可以高产率或高产率有效地转化为其相应的N，N-二甲基酰胺。在此协议中，WCl6 / DMF负责Pd（0）催化剂的生成以及Vilsmeier亚胺型中间体的形成。

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《RSC Advances》 |2014年第81期|共5页
作者
Iranpoor Nasser; Firouzabadi Habib; Rizi Zeinab Tavangar; Erfan Soodabeh;
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中图分类化学;
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1. WCl6/DMF as a new reagent system for the phosphine-free Pd(0)-catalyzed aminocarbonylation of aryl halides [J] . Iranpoor Nasser, Firouzabadi Habib, Rizi Zeinab Tavangar, RSC Advances . 2014,第81期

机译：WCl6 / DMF作为无膦Pd（0）催化的芳基卤化物氨基羰基化的新试剂系统
2. Palladium-catalyzed carbonylation of aryl halides: an efficient, heterogeneous and phosphine-free catalytic system for aminocarbonylation and alkoxycarbonylation employing Mo(CO)6 as a solid carbon monoxide source [J] . Abdol-Reza Hajipour, Zeinab Tavangar-Rizi, Nasser Iranpoor RSC Advances . 2016,第82期

机译：芳基卤化物的钯催化羰基化：用于氨基羰基化的有效，非均相和膦 - 无膦催化系统，其使用Mo（CO）6作为固体一氧化碳源的烷氧基羰基化
3. Mild and efficient Pd((PBu3)-Bu-t)(2)-catalyzed aminocarbonylation of aryl halides to aryl amides with high selectivity [J] . Lei Yizhu, Xiao Se, Li Guangxing, Applied Organometallic Chemistry . 2017,第7期

机译：温和和高效的Pd（（pbu3）-bu-t）（2） - 芳基卤化物的催化氨基羰基化与具有高选择性的芳基酰胺
4. Iron-Catalyzed Cross-Coupling of Alkyl Halides with Aryl Zinc Reagents [C] . Shingo Ito, Eiichi Nakamura, Masaharu Nakamura Symposium on Organometallic Chemistry . 2006

机译：用芳基锌试剂的铁催化烷基卤化物的交联偶联
5. Mechanism of the palladium-catalyzed amination of aryl halides: Kinetic studies of the oxidative addition of aryl halides and sulfonates to phosphine complexes of Pd(0) and of the catalytic reaction of amines with aryl halides and base. [D] . Alcazar-Roman, Luis Manuel. 2001

机译：钯催化芳基卤化物胺化的机理：动力学研究氧化芳基卤化物和磺酸盐到Pd（0）的膦配合物中，以及胺与芳基卤化物和碱的催化反应。
6. Cobalt-catalyzed aminocarbonylation of (hetero)aryl halides promoted by visible light [O] . Alexander M. Veatch, Erik J. Alexanian 2020

机译：通过可见光促进的（杂）芳基卤化物的钴催化的氨基羰基化
7. Recyclable Electron Transfer System: Electroreduction of Viologen in Ionic Liquids and Pd-catalyzed Reductive Coupling of Aryl Halides [O] . Manabu KUROBOSHI, Akiko KUWANO, Hideo TANAKA 2008

机译：可回收电子转移系统：在离子液体中的violologen电导和芳基卤化物的PD催化还原偶联

WCl6/DMF as a new reagent system for the phosphine-free Pd(0)-catalyzed aminocarbonylation of aryl halides

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