Enantioselective addition of ArTi((OPr)-Pr-i)(3) to aldehydes catalyzed by a titanium complex of an N-sulfonylated amino alcohol

Chang Shih-Ju; Zhou Shuangliu; Gau Han-Mou

首页> 外文期刊>RSC Advances >Enantioselective addition of ArTi((OPr)-Pr-i)(3) to aldehydes catalyzed by a titanium complex of an N-sulfonylated amino alcohol

【24h】

Enantioselective addition of ArTi((OPr)-Pr-i)(3) to aldehydes catalyzed by a titanium complex of an N-sulfonylated amino alcohol

机译：N-磺酰化氨基醇的钛络合物催化将ArTi（（OPr）-Pr-i）（3）对映选择性加成到醛中

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Asymmetric additions of ArTi((OPr)-Pr-i)(3) to aldehydes catalyzed by a titanium catalyst of N-sulfonylated amino alcohols were reported, and results showed that the chiral N-sulfonylated amino alcohol with two stereogenic centers could catalyze the asymmetric addition of ArTi((OPr)-Pr-i)(3) to aldehydes to afford desired secondary alcohols in good yields with good to excellent enantioselectivities of up to 95% ee.

机译：据报道，N-磺酰化氨基醇的钛催化剂催化的醛中不对称地添加了ArTi（（OPr）-Pr-i）（3），结果表明，具有两个立体中心的手性N-磺酰化氨基醇可以催化向醛中不对称地添加ArTi（（OPr）-Pr-i）（3），以高收率提供所需的仲醇，并具有高达95％ee的良好至优异的对映选择性。

著录项

来源
《RSC Advances》 |2015年第13期|共6页
作者
Chang Shih-Ju; Zhou Shuangliu; Gau Han-Mou;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Enantioselective addition of ArTi((OPr)-Pr-i)(3) to aldehydes catalyzed by a titanium complex of an N-sulfonylated amino alcohol [J] . Chang Shih-Ju, Zhou Shuangliu, Gau Han-Mou RSC Advances . 2015,第13期

机译：N-磺酰化氨基醇的钛络合物催化将ArTi（（OPr）-Pr-i）（3）对映选择性加成到醛中
2. Polystyrene-supported N-sulfonylated amino alcohols and their applications to titanium(IV) complexes catalyzed enantioselective diethylzinc additions to aldehydes [J] . Hui XP, Chen CA, Wu KH, Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2007,第1期

机译：聚苯乙烯负载的N-磺酰化氨基醇及其在钛（IV）络合物上的催化醛的对映选择性二乙基锌加成反应
3. Enantioselective addition of diethylzinc to aldehydes catalyzed by Titanium(IV) complexes of N-sulfonylated beta-amino alcohols with four stereogenic centers [J] . Hsieh SS, Gau HM Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2006,第8期

机译：N-磺酰化β-氨基醇的钛（IV）配合物与四个立体生成中心催化的二乙基锌对醛的对映选择性加成
4. Enantioselective Addition of Terminal Alkynes to Aldehydes Catalyzed by a Copper(I)-TRAP Complex [C] . Yohsuke Asano, Hajime Ito, Masaya Sawamura Symposium on Organometallic Chemistry . 2007

机译：将终端炔烃对铜（I） - 综合复合物催化的末端炔烃加入醛
5. Studies in asymmetric catalysis: Lewis base catalyzed, enantioselective addition of trimethylsilyl cyanide, trimethylsilyltrifluoromethane, and glycolate-derived silyl ketene acetals to aldehydes [D] . Chung, Won-Jin 2008

机译：不对称催化的研究：路易斯碱催化，对映选择性地将三甲基甲硅烷基氰化物，三甲基甲硅烷基三氟甲烷和乙醇酸衍生的甲硅烷基烯酮缩醛加成醛
6. Highly Enantioselective Addition of Phenylethynylzinc to Aldehydes Catalyzed by Chiral Cyclopropane-Based Amino Alcohols [O] . Bing Zheng, Zhiyuan Li, Feipeng Liu, 2013

机译：手性环丙烷基氨基醇催化苯乙炔锌向醛的高度对映选择性加成
7. Highly Enantioselective Cyanosilylation of Aldehydes Catalyzed by Novel b-Amino Alcohol-Titanium Complexes [O] . -1

机译：通过新型B-氨基醇 - 钛配合物催化的高映射氰基甲硅烷化物

Enantioselective addition of ArTi((OPr)-Pr-i)(3) to aldehydes catalyzed by a titanium complex of an N-sulfonylated amino alcohol

摘要

著录项

相似文献

相关主题

期刊订阅