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Bunching and antibunching in the fluorescence of semiconductor nanocrystals

机译:半导体纳米晶体荧光中的聚束和反聚束

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摘要

The fluorescence of single-colloidal CdSe quantum dots is investigated at room temperature by means of the autocorrelation function over a time scale of almost 12 orders of magnitude. Over a short time scale, the autocorrelation function shows complete antibunching, indicating single-photon emission and atomiclike behavior. Over longer time scales (up to tens of seconds), we measure a bunching effect that is due to fluorescence intermittency and that cannot be described by fluctuations between two states with constant rates. The autocorrelation function also exhibits nonstationary behavior related to power-law distributions of ON and OFF times.
机译:在室温下,通过自相关函数,在大约12个数量级的时间范围内研究了单胶体CdSe量子点的荧光。在短时间内,自相关函数显示出完全的反聚束,表明单光子发射和类似原子的行为。在更长的时间范围内(长达数十秒),我们测量的是由于荧光的间歇性引起的聚束效应,并且不能用恒定速率的两个状态之间的波动来描述。自相关函数还表现出与ON和OFF时间的幂律分布有关的非平稳行为。

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